Vortex assisted-supramolecular solvent based microextraction coupled with spectrophotometric determination of triclosan in environmental water samples

A simple, fast and environmental friendly vortex assisted-supramolecular solvent based microextraction (VA-SSME) method was developed for the preconcetration of triclosan in wastewater prior to UV spectrophotometric determination. To achieve maximum sensitivity and accuracy for the target analyte, the experimental parameters affecting the VA-SSME procedure were optimized using response surface methodology (RSM). Under optimised conditions, the correlation coefficient (R²) and recoveries were 0.9994 and 100.31-118.5%, respectively. The intra-day (repeatability) and inter-day (reproducibility) precisions expressed in terms of relative standard deviation (RSD) were 2-4% and 5.2%, respectively. The preconcentration factor and limits of detection (LOD) and quantification (LOQ) were found to be 90, 0.28 μg L^-1 and 0.92 μg L^-1, respectively. The developed VA-SSME/UV method was applied for the determination of triclosan in real samples collected over a period of three months. The analytical results obtained showed that triclosan was frequently detected in influent wastewater samples but was not detected in effluent samples.