Valence isomerization of phosphepines

Helen Jansen; J. Chris Slootweg; Andreas W. Ehlers; Koop Lammertsma

doi:10.1021/om1004379

Valence isomerization of phosphepines

Helen Jansen
, J. Chris Slootweg
, Andreas W. Ehlers
, Koop Lammertsma

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

Original language	English
Pages (from-to)	6653-6659
Number of pages	7
Journal	Organometallics
Volume	29
Issue number	24
DOIs	https://doi.org/10.1021/om1004379
Publication status	Published - 27 Dec 2010
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om1004379

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title = "Valence isomerization of phosphepines",

abstract = "Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.",

author = "Helen Jansen and Slootweg, \{J. Chris\} and Ehlers, \{Andreas W.\} and Koop Lammertsma",

year = "2010",

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doi = "10.1021/om1004379",

language = "English",

volume = "29",

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journal = "Organometallics",

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T1 - Valence isomerization of phosphepines

AU - Jansen, Helen

AU - Slootweg, J. Chris

AU - Ehlers, Andreas W.

AU - Lammertsma, Koop

PY - 2010/12/27

Y1 - 2010/12/27

N2 - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

AB - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

UR - https://www.scopus.com/pages/publications/78650634665

U2 - 10.1021/om1004379

DO - 10.1021/om1004379

M3 - Article

AN - SCOPUS:78650634665

SN - 0276-7333

VL - 29

SP - 6653

EP - 6659

JO - Organometallics

JF - Organometallics

IS - 24

ER -

Valence isomerization of phosphepines

Abstract

ASJC Scopus subject areas

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