Valence isomerization of phosphepines

Helen Jansen; J. Chris Slootweg; Andreas W. Ehlers; Koop Lammertsma

doi:10.1021/om1004379

Valence isomerization of phosphepines

Helen Jansen, J. Chris Slootweg, Andreas W. Ehlers, Koop Lammertsma

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

Original language	English
Pages (from-to)	6653-6659
Number of pages	7
Journal	Organometallics
Volume	29
Issue number	24
DOIs	https://doi.org/10.1021/om1004379
Publication status	Published - 27 Dec 2010
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om1004379

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title = "Valence isomerization of phosphepines",

abstract = "Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.",

author = "Helen Jansen and Slootweg, {J. Chris} and Ehlers, {Andreas W.} and Koop Lammertsma",

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AU - Jansen, Helen

AU - Slootweg, J. Chris

AU - Ehlers, Andreas W.

AU - Lammertsma, Koop

PY - 2010/12/27

Y1 - 2010/12/27

N2 - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

AB - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents.

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U2 - 10.1021/om1004379

DO - 10.1021/om1004379

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AN - SCOPUS:78650634665

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SP - 6653

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JO - Organometallics

JF - Organometallics

IS - 24

ER -

Valence isomerization of phosphepines

Abstract

ASJC Scopus subject areas

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