Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

Helen Jansen; J. Chris Slootweg; Koop Lammertsma

doi:10.3762/bjoc.7.201

Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

Helen Jansen, J. Chris Slootweg, Koop Lammertsma

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.

Original language	English
Pages (from-to)	1713-1721
Number of pages	9
Journal	Beilstein Journal of Organic Chemistry
Volume	7
DOIs	https://doi.org/10.3762/bjoc.7.201
Publication status	Published - 21 Dec 2011
Externally published	Yes

Keywords

Aromaticity
Cycloheptatriene
Heteroatom
Valence isomerization

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.7.201

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abstract = "The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.",

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author = "Helen Jansen and {Chris Slootweg}, J. and Koop Lammertsma",

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AU - Jansen, Helen

AU - Chris Slootweg, J.

AU - Lammertsma, Koop

PY - 2011/12/21

Y1 - 2011/12/21

N2 - The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.

AB - The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.

KW - Aromaticity

KW - Cycloheptatriene

KW - Heteroatom

KW - Valence isomerization

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DO - 10.3762/bjoc.7.201

M3 - Article

AN - SCOPUS:84455189162

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JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

Abstract

Keywords

ASJC Scopus subject areas

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