Unconjugated diimine palladium complexes as Heck coupling catalysts

Simphiwe M. Nelana; Jezreel Cloete; George C. Lisensky; Ebbe Nordlander; Ilia A. Guzei; Selwyn F. Mapolie; James Darkwa

doi:10.1016/j.molcata.2008.01.009

Unconjugated diimine palladium complexes as Heck coupling catalysts

Simphiwe M. Nelana, Jezreel Cloete, George C. Lisensky, Ebbe Nordlander, Ilia A. Guzei, Selwyn F. Mapolie, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

Original language	English
Pages (from-to)	72-78
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	285
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2008.01.009
Publication status	Published - 18 Apr 2008

Keywords

Crystal structures
Heck coupling catalysts
Palladium complexes
Unconjugated diimine ligands

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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10.1016/j.molcata.2008.01.009

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title = "Unconjugated diimine palladium complexes as Heck coupling catalysts",

abstract = "Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.",

keywords = "Crystal structures, Heck coupling catalysts, Palladium complexes, Unconjugated diimine ligands",

author = "Nelana, {Simphiwe M.} and Jezreel Cloete and Lisensky, {George C.} and Ebbe Nordlander and Guzei, {Ilia A.} and Mapolie, {Selwyn F.} and James Darkwa",

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T1 - Unconjugated diimine palladium complexes as Heck coupling catalysts

AU - Nelana, Simphiwe M.

AU - Cloete, Jezreel

AU - Lisensky, George C.

AU - Nordlander, Ebbe

AU - Guzei, Ilia A.

AU - Mapolie, Selwyn F.

AU - Darkwa, James

PY - 2008/4/18

Y1 - 2008/4/18

N2 - Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

AB - Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

KW - Crystal structures

KW - Heck coupling catalysts

KW - Palladium complexes

KW - Unconjugated diimine ligands

UR - http://www.scopus.com/inward/record.url?scp=43049084714&partnerID=8YFLogxK

U2 - 10.1016/j.molcata.2008.01.009

DO - 10.1016/j.molcata.2008.01.009

M3 - Article

AN - SCOPUS:43049084714

SN - 1381-1169

VL - 285

SP - 72

EP - 78

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Unconjugated diimine palladium complexes as Heck coupling catalysts

Abstract

Keywords

ASJC Scopus subject areas

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