Tris(naphthalen-1-yl)phosphane chloroform hemisolvate

Wade L. Davis; Alfred Muller

doi:10.1107/S1600536812048234

Tris(naphthalen-1-yl)phosphane chloroform hemisolvate

Wade L. Davis
, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris(naphthalen-1-yl)phosphane. The solvent molecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H⋯Cl and C-H⋯π interactions are observed.

Original language	English
Pages (from-to)	o3484
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812048234
Publication status	Published - Dec 2012

Keywords

R factor = 0.066
T = 100 K
data-toparameter ratio = 18.8
disorder in solvent or counterion
mean ω(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.194

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536812048234

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title = "Tris(naphthalen-1-yl)phosphane chloroform hemisolvate",

abstract = "The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris(naphthalen-1-yl)phosphane. The solvent molecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H⋯Cl and C-H⋯π interactions are observed.",

keywords = "R factor = 0.066, T = 100 K, data-toparameter ratio = 18.8, disorder in solvent or counterion, mean ω(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.194",

author = "Davis, \{Wade L.\} and Alfred Muller",

year = "2012",

month = dec,

doi = "10.1107/S1600536812048234",

language = "English",

volume = "68",

pages = "o3484",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Tris(naphthalen-1-yl)phosphane chloroform hemisolvate

AU - Davis, Wade L.

AU - Muller, Alfred

PY - 2012/12

Y1 - 2012/12

N2 - The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris(naphthalen-1-yl)phosphane. The solvent molecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H⋯Cl and C-H⋯π interactions are observed.

AB - The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris(naphthalen-1-yl)phosphane. The solvent molecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H⋯Cl and C-H⋯π interactions are observed.

KW - R factor = 0.066

KW - T = 100 K

KW - data-toparameter ratio = 18.8

KW - disorder in solvent or counterion

KW - mean ω(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.194

UR - https://www.scopus.com/pages/publications/84870914038

U2 - 10.1107/S1600536812048234

DO - 10.1107/S1600536812048234

M3 - Article

AN - SCOPUS:84870914038

SN - 1600-5368

VL - 68

SP - o3484

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Tris(naphthalen-1-yl)phosphane chloroform hemisolvate

Abstract

Keywords

ASJC Scopus subject areas

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