Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)

Kariska Potgieter; Frederick P. Malan; Oyekunle Azeez Alimi; Reinout Meijboom

doi:10.1107/S2414314622011476

Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

Kariska Potgieter, Frederick P. Malan, Oyekunle Azeez Alimi, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C-H⋯O interactions consolidate the packing.

Original language	English
Article number	x221147
Journal	IUCrData
Volume	7
DOIs	https://doi.org/10.1107/S2414314622011476
Publication status	Published - 6 Dec 2022

Keywords

crystal structure
silver(I) phosphine inorganic complex

ASJC Scopus subject areas

Analytical Chemistry
Inorganic Chemistry
Organic Chemistry

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10.1107/S2414314622011476

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title = "Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)",

abstract = "The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) {\AA}, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) {\AA} is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C-H⋯O interactions consolidate the packing.",

keywords = "crystal structure, silver(I) phosphine inorganic complex",

author = "Kariska Potgieter and Malan, {Frederick P.} and Alimi, {Oyekunle Azeez} and Reinout Meijboom",

year = "2022",

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day = "6",

doi = "10.1107/S2414314622011476",

language = "English",

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T1 - Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

AU - Potgieter, Kariska

AU - Malan, Frederick P.

AU - Alimi, Oyekunle Azeez

AU - Meijboom, Reinout

PY - 2022/12/6

Y1 - 2022/12/6

N2 - The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C-H⋯O interactions consolidate the packing.

AB - The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C-H⋯O interactions consolidate the packing.

KW - crystal structure

KW - silver(I) phosphine inorganic complex

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DO - 10.1107/S2414314622011476

M3 - Article

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SN - 2414-3146

VL - 7

JO - IUCrData

JF - IUCrData

M1 - x221147

ER -

Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

Abstract

Keywords

ASJC Scopus subject areas

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Cite this

Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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Fingerprint

Cite this

Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)