Triferrocenylphosphine oxide monohydrate

Alfred Muller; Gideon Steyl; Andreas Roodt

doi:10.1107/S0108270104014908

Triferrocenylphosphine oxide monohydrate

Alfred Muller, Gideon Steyl, Andreas Roodt

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [Fe₃(C₅H₅) ₃(C₁₅H₁₂OP)]·H₂O or Fc ₃PO·-H₂O, was obtained as red crystals from the Friedel-Crafts alkylation reaction of PCl₃ and ferrocene. Torsion angles (O=P-C-Fe/C) range from -45.39 (9) to -56.11 (14)°. The structure is stabilized by intermolecular hydrogen bonds [H·O = 2.10 (3) and 2.00 (4) Å], forming dimeric structures between pairs of O=PFc₃ and water molecules. A theoretical Tolman cone angle of 211° was calculated.

Original language	English
Pages (from-to)	m386-m388
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S0108270104014908
Publication status	Published - Aug 2004

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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@article{56705ec72dfe483aa01cd35b26fe2aec,

title = "Triferrocenylphosphine oxide monohydrate",

abstract = "The title compound, [Fe3(C5H5) 3(C15H12OP)]·H2O or Fc 3PO·-H2O, was obtained as red crystals from the Friedel-Crafts alkylation reaction of PCl3 and ferrocene. Torsion angles (O=P-C-Fe/C) range from -45.39 (9) to -56.11 (14)°. The structure is stabilized by intermolecular hydrogen bonds [H·O = 2.10 (3) and 2.00 (4) {\AA}], forming dimeric structures between pairs of O=PFc3 and water molecules. A theoretical Tolman cone angle of 211° was calculated.",

author = "Alfred Muller and Gideon Steyl and Andreas Roodt",

year = "2004",

month = aug,

doi = "10.1107/S0108270104014908",

language = "English",

volume = "60",

pages = "m386--m388",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Triferrocenylphosphine oxide monohydrate

AU - Muller, Alfred

AU - Steyl, Gideon

AU - Roodt, Andreas

PY - 2004/8

Y1 - 2004/8

N2 - The title compound, [Fe3(C5H5) 3(C15H12OP)]·H2O or Fc 3PO·-H2O, was obtained as red crystals from the Friedel-Crafts alkylation reaction of PCl3 and ferrocene. Torsion angles (O=P-C-Fe/C) range from -45.39 (9) to -56.11 (14)°. The structure is stabilized by intermolecular hydrogen bonds [H·O = 2.10 (3) and 2.00 (4) Å], forming dimeric structures between pairs of O=PFc3 and water molecules. A theoretical Tolman cone angle of 211° was calculated.

AB - The title compound, [Fe3(C5H5) 3(C15H12OP)]·H2O or Fc 3PO·-H2O, was obtained as red crystals from the Friedel-Crafts alkylation reaction of PCl3 and ferrocene. Torsion angles (O=P-C-Fe/C) range from -45.39 (9) to -56.11 (14)°. The structure is stabilized by intermolecular hydrogen bonds [H·O = 2.10 (3) and 2.00 (4) Å], forming dimeric structures between pairs of O=PFc3 and water molecules. A theoretical Tolman cone angle of 211° was calculated.

UR - https://www.scopus.com/pages/publications/4444310974

U2 - 10.1107/S0108270104014908

DO - 10.1107/S0108270104014908

M3 - Article

AN - SCOPUS:4444310974

SN - 0108-2701

VL - 60

SP - m386-m388

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 8

ER -

Triferrocenylphosphine oxide monohydrate

Abstract

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