Transport of MMA through SBR for fabrication of IPN based on Cross-linked SBR and PMMA

Jose James; George V. Thomas; Sabu Thomas

doi:10.1088/1757-899X/360/1/012035

Transport of MMA through SBR for fabrication of IPN based on Cross-linked SBR and PMMA

Jose James, George V. Thomas, Sabu Thomas

Research output: Contribution to journal › Conference article › peer-review

Abstract

The diffusion and transport of inhibitor-free Methyl methacrylate (MMA) monomers through cross-linked Styrene Butadiene Rubber (SBR) have been studied at various temperatures and is compared with its transport through Natural Rubber (NR). SBR has been vulcanized by conventional, efficient and peroxide vulcanization techniques. The dependence of diffusion rate on the crosslinking system, cross -link density, size of the penetrant, thickness of the matrix and type of polymer matrices have been studied for the systems. The influence of temperature on the sorption has been evaluated using the diffusion data. The peroxide system showed lowest uptake and the effective system showed highest uptake. Mechanism of transport of MMA through SBR system was also reported in this paper and it follows Fickian mode of transport.

Original language	English
Article number	012035
Journal	IOP Conference Series: Materials Science and Engineering
Volume	360
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/360/1/012035
Publication status	Published - 2018
Externally published	Yes
Event	2nd International Conference on Materials Science and Technology, ICMST 2016 - Kerala, India Duration: 5 Jun 2016 → 8 Jun 2016

Keywords

Cross-linked SBR
Fickian mode of transport
NR
diffusion
sorption

ASJC Scopus subject areas

General Materials Science
General Engineering

Access to Document

10.1088/1757-899X/360/1/012035

Cite this

@article{357303a33e9b4e019ee5fb234e314f4a,

title = "Transport of MMA through SBR for fabrication of IPN based on Cross-linked SBR and PMMA",

abstract = "The diffusion and transport of inhibitor-free Methyl methacrylate (MMA) monomers through cross-linked Styrene Butadiene Rubber (SBR) have been studied at various temperatures and is compared with its transport through Natural Rubber (NR). SBR has been vulcanized by conventional, efficient and peroxide vulcanization techniques. The dependence of diffusion rate on the crosslinking system, cross -link density, size of the penetrant, thickness of the matrix and type of polymer matrices have been studied for the systems. The influence of temperature on the sorption has been evaluated using the diffusion data. The peroxide system showed lowest uptake and the effective system showed highest uptake. Mechanism of transport of MMA through SBR system was also reported in this paper and it follows Fickian mode of transport.",

keywords = "Cross-linked SBR, Fickian mode of transport, NR, diffusion, sorption",

author = "Jose James and Thomas, \{George V.\} and Sabu Thomas",

note = "Publisher Copyright: {\textcopyright} 2018 Institute of Physics Publishing. All rights reserved.; 2nd International Conference on Materials Science and Technology, ICMST 2016 ; Conference date: 05-06-2016 Through 08-06-2016",

year = "2018",

doi = "10.1088/1757-899X/360/1/012035",

language = "English",

volume = "360",

journal = "IOP Conference Series: Materials Science and Engineering",

issn = "1757-8981",

publisher = "IOP Publishing Ltd.",

number = "1",

}

TY - JOUR

T1 - Transport of MMA through SBR for fabrication of IPN based on Cross-linked SBR and PMMA

AU - James, Jose

AU - Thomas, George V.

AU - Thomas, Sabu

PY - 2018

Y1 - 2018

N2 - The diffusion and transport of inhibitor-free Methyl methacrylate (MMA) monomers through cross-linked Styrene Butadiene Rubber (SBR) have been studied at various temperatures and is compared with its transport through Natural Rubber (NR). SBR has been vulcanized by conventional, efficient and peroxide vulcanization techniques. The dependence of diffusion rate on the crosslinking system, cross -link density, size of the penetrant, thickness of the matrix and type of polymer matrices have been studied for the systems. The influence of temperature on the sorption has been evaluated using the diffusion data. The peroxide system showed lowest uptake and the effective system showed highest uptake. Mechanism of transport of MMA through SBR system was also reported in this paper and it follows Fickian mode of transport.

AB - The diffusion and transport of inhibitor-free Methyl methacrylate (MMA) monomers through cross-linked Styrene Butadiene Rubber (SBR) have been studied at various temperatures and is compared with its transport through Natural Rubber (NR). SBR has been vulcanized by conventional, efficient and peroxide vulcanization techniques. The dependence of diffusion rate on the crosslinking system, cross -link density, size of the penetrant, thickness of the matrix and type of polymer matrices have been studied for the systems. The influence of temperature on the sorption has been evaluated using the diffusion data. The peroxide system showed lowest uptake and the effective system showed highest uptake. Mechanism of transport of MMA through SBR system was also reported in this paper and it follows Fickian mode of transport.

KW - Cross-linked SBR

KW - Fickian mode of transport

KW - NR

KW - diffusion

KW - sorption

UR - https://www.scopus.com/pages/publications/85056613738

U2 - 10.1088/1757-899X/360/1/012035

DO - 10.1088/1757-899X/360/1/012035

M3 - Conference article

AN - SCOPUS:85056613738

SN - 1757-8981

VL - 360

JO - IOP Conference Series: Materials Science and Engineering

JF - IOP Conference Series: Materials Science and Engineering

IS - 1

M1 - 012035

T2 - 2nd International Conference on Materials Science and Technology, ICMST 2016

Y2 - 5 June 2016 through 8 June 2016

ER -

Transport of MMA through SBR for fabrication of IPN based on Cross-linked SBR and PMMA

Abstract

Keywords

ASJC Scopus subject areas

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