Trans-dichlorobis[tris(4-fluorophenyl)-phosphine]palladium(II) toluene solvate

Reinout Meijboom; Alfred Muller; Andreas Roodt; J. Marthinus Janse Van Rensburg

doi:10.1107/S1600536806010579

Trans-dichlorobis[tris(4-fluorophenyl)-phosphine]palladium(II) toluene solvate

Reinout Meijboom, Alfred Muller, Andreas Roodt, J. Marthinus Janse Van Rensburg

University of The Free State

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, trans-[PdCl₂{P(C₆H ₄F)₃}₂]·C₇H₈, where P(C₆H₄F)₃ is tris(4-fluorophenyl) phosphine, crystallizes with both molecules in special positions. The trans-[PdCl₂-{P(C₆H₄F)₃} ₂] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd-P and Pd-Cl distances are 2.3398(12) and 2.2955 (13) Å, respectively, and the P-Pd-Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.

Original language	English
Pages (from-to)	m894-m896
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	4
DOIs	https://doi.org/10.1107/S1600536806010579
Publication status	Published - 1 Apr 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-dichlorobis[tris(4-fluorophenyl)-phosphine]palladium(II) toluene solvate",

abstract = "The title compound, trans-[PdCl2{P(C6H 4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl) phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2-{P(C6H4F)3} 2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd-P and Pd-Cl distances are 2.3398(12) and 2.2955 (13) {\AA}, respectively, and the P-Pd-Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.",

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T1 - Trans-dichlorobis[tris(4-fluorophenyl)-phosphine]palladium(II) toluene solvate

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

AU - Van Rensburg, J. Marthinus Janse

PY - 2006/4/1

Y1 - 2006/4/1

N2 - The title compound, trans-[PdCl2{P(C6H 4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl) phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2-{P(C6H4F)3} 2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd-P and Pd-Cl distances are 2.3398(12) and 2.2955 (13) Å, respectively, and the P-Pd-Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.

AB - The title compound, trans-[PdCl2{P(C6H 4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl) phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2-{P(C6H4F)3} 2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd-P and Pd-Cl distances are 2.3398(12) and 2.2955 (13) Å, respectively, and the P-Pd-Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.

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Trans-dichlorobis[tris(4-fluorophenyl)-phosphine]palladium(II) toluene solvate

Abstract

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