Trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536806022264

Trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)

Reinout Meijboom, Alfred Muller, Andreas Roodt

University of The Free State

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the title compound, trans-[pdCl₂(P(C₇H ₇)₃}₂], where P(C₇H ₇)₃ is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd-P and Pd-Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P-Pd-Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165.

Original language	English
Pages (from-to)	m1603-m1605
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	7
DOIs	https://doi.org/10.1107/S1600536806022264
Publication status	Published - Jul 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{f0db1c59bcd147e4b93da872aa89c320,

title = "Trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)",

abstract = "In the title compound, trans-[pdCl2(P(C7H 7)3}2], where P(C7H 7)3 is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd-P and Pd-Cl distances of 2.3289 (4) and 2.2897 (4) {\AA}, respectively, and a P-Pd-Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2006",

month = jul,

doi = "10.1107/S1600536806022264",

language = "English",

volume = "62",

pages = "m1603--m1605",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "7",

}

TY - JOUR

T1 - Trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2006/7

Y1 - 2006/7

N2 - In the title compound, trans-[pdCl2(P(C7H 7)3}2], where P(C7H 7)3 is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd-P and Pd-Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P-Pd-Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165.

AB - In the title compound, trans-[pdCl2(P(C7H 7)3}2], where P(C7H 7)3 is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd-P and Pd-Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P-Pd-Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165.

UR - http://www.scopus.com/inward/record.url?scp=33745985687&partnerID=8YFLogxK

U2 - 10.1107/S1600536806022264

DO - 10.1107/S1600536806022264

M3 - Article

AN - SCOPUS:33745985687

SN - 1600-5368

VL - 62

SP - m1603-m1605

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)

Abstract

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