Trans-Dichlorobis(cyclohexyldiphenylphosphine)-palladium(ll)

Anna M.M. Meij; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536802022924

Trans-Dichlorobis(cyclohexyldiphenylphosphine)-palladium(ll)

Anna M.M. Meij, Alfred Muller, Andreas Roodt

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

As part of a systematic investigation for a number of Pd^II complexes in order to find correlations between molecular structure and chemical behaviour, crystals of the title compound, trans-[PdCl₂(PPh ₂Cy)₂] or [PdCl₂(C₁₈H ₂₁P)₂], were prepared. The Pd atom is located on an inversion cneter. Selected geometrical parameters are: Pd-P 2.3256 (10) and Pd-Cl 2.3007 (11) Å, and P-Pd-Cl 91.38 (4)°. The effective and Tolman cone angles for the PPh₂Cy ligand were determined as 151.0 and 154.6°, respectively.

Original language	English
Pages (from-to)	m44-m45
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	1
DOIs	https://doi.org/10.1107/S1600536802022924
Publication status	Published - Jan 2003

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-Dichlorobis(cyclohexyldiphenylphosphine)-palladium(ll)",

abstract = "As part of a systematic investigation for a number of PdII complexes in order to find correlations between molecular structure and chemical behaviour, crystals of the title compound, trans-[PdCl2(PPh 2Cy)2] or [PdCl2(C18H 21P)2], were prepared. The Pd atom is located on an inversion cneter. Selected geometrical parameters are: Pd-P 2.3256 (10) and Pd-Cl 2.3007 (11) {\AA}, and P-Pd-Cl 91.38 (4)°. The effective and Tolman cone angles for the PPh2Cy ligand were determined as 151.0 and 154.6°, respectively.",

author = "Meij, {Anna M.M.} and Alfred Muller and Andreas Roodt",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Trans-Dichlorobis(cyclohexyldiphenylphosphine)-palladium(ll)

AU - Meij, Anna M.M.

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2003/1

Y1 - 2003/1

N2 - As part of a systematic investigation for a number of PdII complexes in order to find correlations between molecular structure and chemical behaviour, crystals of the title compound, trans-[PdCl2(PPh 2Cy)2] or [PdCl2(C18H 21P)2], were prepared. The Pd atom is located on an inversion cneter. Selected geometrical parameters are: Pd-P 2.3256 (10) and Pd-Cl 2.3007 (11) Å, and P-Pd-Cl 91.38 (4)°. The effective and Tolman cone angles for the PPh2Cy ligand were determined as 151.0 and 154.6°, respectively.

AB - As part of a systematic investigation for a number of PdII complexes in order to find correlations between molecular structure and chemical behaviour, crystals of the title compound, trans-[PdCl2(PPh 2Cy)2] or [PdCl2(C18H 21P)2], were prepared. The Pd atom is located on an inversion cneter. Selected geometrical parameters are: Pd-P 2.3256 (10) and Pd-Cl 2.3007 (11) Å, and P-Pd-Cl 91.38 (4)°. The effective and Tolman cone angles for the PPh2Cy ligand were determined as 151.0 and 154.6°, respectively.

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DO - 10.1107/S1600536802022924

M3 - Article

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SN - 1600-5368

VL - 59

SP - m44-m45

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Trans-Dichlorobis(cyclohexyldiphenylphosphine)-palladium(ll)

Abstract

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