Trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate

Alfred Muller

doi:10.1107/S1600536812045643

Trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate

Alfred Muller

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a Pt^II ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The Pt^II ion is coordinated by two P atoms [Pt-P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt-Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P-Pt-Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C-H⋯O and C-H⋯Cl hydrogen bonds hold molecules together.

Original language	English
Pages (from-to)	m1475
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812045643
Publication status	Published - Dec 2012

Keywords

R factor = 0.019
T = 100 K
data-to-parameter ratio = 20.6
mean ω(C-C) = 0.003 Å
single-crystal X-ray study
wR factor = 0.040

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536812045643

Cite this

@article{a09d511da21e418facb4b0ee3794323d,

title = "Trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate",

abstract = "In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt-P = 2.3196 (5) {\AA}] from two L ligands and two chloride anions [Pt-Cl = 2.3075 (5) {\AA}] in a distorted square-planar geometry with P-Pt-Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C-H⋯O and C-H⋯Cl hydrogen bonds hold molecules together.",

keywords = "R factor = 0.019, T = 100 K, data-to-parameter ratio = 20.6, mean ω(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.040",

author = "Alfred Muller",

year = "2012",

month = dec,

doi = "10.1107/S1600536812045643",

language = "English",

volume = "68",

pages = "m1475",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate

AU - Muller, Alfred

PY - 2012/12

Y1 - 2012/12

N2 - In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt-P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt-Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P-Pt-Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C-H⋯O and C-H⋯Cl hydrogen bonds hold molecules together.

AB - In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt-P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt-Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P-Pt-Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C-H⋯O and C-H⋯Cl hydrogen bonds hold molecules together.

KW - R factor = 0.019

KW - T = 100 K

KW - data-to-parameter ratio = 20.6

KW - mean ω(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.040

UR - http://www.scopus.com/inward/record.url?scp=84870886001&partnerID=8YFLogxK

U2 - 10.1107/S1600536812045643

DO - 10.1107/S1600536812045643

M3 - Article

AN - SCOPUS:84870886001

SN - 1600-5368

VL - 68

SP - m1475

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this