Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate

Charmaine Van Blerk; Cedric W. Holzapfel

doi:10.1107/S1600536809046261

Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate

Charmaine Van Blerk, Cedric W. Holzapfel

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The structure of the title compound, [PdCl2(C₂₁H ₂₁O₃P)2]·C₆H₆, shows a square-planar geometry for the Pd^II atom within a Cl2[P(PhOMe)3]2 ligand set. The crystal structure contains benzene as solvent. The Pd ^II atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd^II atom, one Cl atom, one tris-(4-methoxy-phen- yl)phosphine ligand and one half of the benzene solvent mol-ecule.

Original language	English
Pages (from-to)	m1536
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	12
DOIs	https://doi.org/10.1107/S1600536809046261
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate",

abstract = "The structure of the title compound, [PdCl2(C21H 21O3P)2]·C6H6, shows a square-planar geometry for the PdII atom within a Cl2[P(PhOMe)3]2 ligand set. The crystal structure contains benzene as solvent. The Pd II atom sits on a centre of inversion and therefore the asymmetric unit contains the PdII atom, one Cl atom, one tris-(4-methoxy-phen- yl)phosphine ligand and one half of the benzene solvent mol-ecule.",

author = "Blerk, {Charmaine Van} and Holzapfel, {Cedric W.}",

year = "2009",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate

AU - Blerk, Charmaine Van

AU - Holzapfel, Cedric W.

PY - 2009

Y1 - 2009

N2 - The structure of the title compound, [PdCl2(C21H 21O3P)2]·C6H6, shows a square-planar geometry for the PdII atom within a Cl2[P(PhOMe)3]2 ligand set. The crystal structure contains benzene as solvent. The Pd II atom sits on a centre of inversion and therefore the asymmetric unit contains the PdII atom, one Cl atom, one tris-(4-methoxy-phen- yl)phosphine ligand and one half of the benzene solvent mol-ecule.

AB - The structure of the title compound, [PdCl2(C21H 21O3P)2]·C6H6, shows a square-planar geometry for the PdII atom within a Cl2[P(PhOMe)3]2 ligand set. The crystal structure contains benzene as solvent. The Pd II atom sits on a centre of inversion and therefore the asymmetric unit contains the PdII atom, one Cl atom, one tris-(4-methoxy-phen- yl)phosphine ligand and one half of the benzene solvent mol-ecule.

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U2 - 10.1107/S1600536809046261

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M3 - Article

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate

Abstract

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