Trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II)

Charmaine Van Blerk; Cedric W. Holzapfel

doi:10.1107/S1600536809040719

Trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II)

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the title compound, [PdCl₂(C₂₁H ₂₁O₃P)₂], shows a nearly square-planar geometry for the Pd^II atom within the Cl₂Pd[P(PhOMe)3]2 ligand set. The Pd^II atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one Pd^II atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.

Original language	English
Pages (from-to)	m1342
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	11
DOIs	https://doi.org/10.1107/S1600536809040719
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II)",

abstract = "The structure of the title compound, [PdCl2(C21H 21O3P)2], shows a nearly square-planar geometry for the PdII atom within the Cl2Pd[P(PhOMe)3]2 ligand set. The PdII atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one PdII atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.",

author = "Blerk, \{Charmaine Van\} and Holzapfel, \{Cedric W.\}",

year = "2009",

doi = "10.1107/S1600536809040719",

language = "English",

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pages = "m1342",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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AU - Blerk, Charmaine Van

AU - Holzapfel, Cedric W.

PY - 2009

Y1 - 2009

N2 - The structure of the title compound, [PdCl2(C21H 21O3P)2], shows a nearly square-planar geometry for the PdII atom within the Cl2Pd[P(PhOMe)3]2 ligand set. The PdII atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one PdII atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.

AB - The structure of the title compound, [PdCl2(C21H 21O3P)2], shows a nearly square-planar geometry for the PdII atom within the Cl2Pd[P(PhOMe)3]2 ligand set. The PdII atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one PdII atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.

UR - https://www.scopus.com/pages/publications/70449421522

U2 - 10.1107/S1600536809040719

DO - 10.1107/S1600536809040719

M3 - Article

AN - SCOPUS:70449421522

SN - 1600-5368

VL - 65

SP - m1342

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II)

Abstract

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