Trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl] phosphane-κP}platinum(II) dichloromethane disolvate

Wade L. Davis; Reinout Meijboom

doi:10.1107/S1600536812048465

Trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl] phosphane-κP}platinum(II) dichloromethane disolvate

Wade L. Davis, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the Pt^II atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt-P and Pt-Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P-Pt-Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148-155].

Original language	English
Pages (from-to)	m1561
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812048465
Publication status	Published - Dec 2012

Keywords

R factor = 0.025
T = 100 K
data-to-parameter ratio = 17.4
mean ω(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.067

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{3b04216ff3894ff1bd88353e0f12e507,

title = "Trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl] phosphane-κP}platinum(II) dichloromethane disolvate",

abstract = "In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt-P and Pt-Cl bond lengths of 2.3258 (6) and 2.3106 (6) {\AA}, respectively, and the P-Pt-Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148-155].",

keywords = "R factor = 0.025, T = 100 K, data-to-parameter ratio = 17.4, mean ω(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.067",

author = "Davis, {Wade L.} and Reinout Meijboom",

year = "2012",

month = dec,

doi = "10.1107/S1600536812048465",

language = "English",

volume = "68",

pages = "m1561",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

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TY - JOUR

T1 - Trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl] phosphane-κP}platinum(II) dichloromethane disolvate

AU - Davis, Wade L.

AU - Meijboom, Reinout

PY - 2012/12

Y1 - 2012/12

N2 - In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt-P and Pt-Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P-Pt-Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148-155].

AB - In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt-P and Pt-Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P-Pt-Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148-155].

KW - R factor = 0.025

KW - T = 100 K

KW - data-to-parameter ratio = 17.4

KW - mean ω(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.067

UR - http://www.scopus.com/inward/record.url?scp=84870916729&partnerID=8YFLogxK

U2 - 10.1107/S1600536812048465

DO - 10.1107/S1600536812048465

M3 - Article

AN - SCOPUS:84870916729

SN - 1600-5368

VL - 68

SP - m1561

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl] phosphane-κP}platinum(II) dichloromethane disolvate

Abstract

Keywords

ASJC Scopus subject areas

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