Trans-Dichloridobis[dicyclohexyl(2,4,6-trimethylphenyl)phosphane-κP] palladium(II)

Isaac Buthelezi; Haleden Chiririwa; Hezron Ogutu; Reinout Meijboom

doi:10.1107/S1600536812040810

Trans-Dichloridobis[dicyclohexyl(2,4,6-trimethylphenyl)phosphane-κP] palladium(II)

Isaac Buthelezi, Haleden Chiririwa, Hezron Ogutu, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [PdCl2(C21H₃3P)2], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd^II atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760(13)Å, while the Pd-Cl bond lengths are 2.3172(14)Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclohexyl(phenyl) phosphane-κP]palladium(II), [PdCl2{P(C6H₁1)2(C6H ₅)}2] [Burgoyne et al. (2012). Acta Cryst. E68, m404].

Original language	English
Pages (from-to)	m1330-m1331
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	11
DOIs	https://doi.org/10.1107/S1600536812040810
Publication status	Published - Nov 2012

Keywords

R factor = 0.061
T = 100 K
data-to-parameter ratio = 22.7
mean ̄(C-C) = 0.008 Å
single-crystal X-ray study
wR factor = 0.165

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{081f459df618460fbc0f29d50ae08d9a,

title = "Trans-Dichloridobis[dicyclohexyl(2,4,6-trimethylphenyl)phosphane-κP] palladium(II)",

abstract = "The title compound, [PdCl2(C21H33P)2], forms a monomeric complex with a trans-square-planar coordination geometry about the PdII atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760(13){\AA}, while the Pd-Cl bond lengths are 2.3172(14){\AA}. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclohexyl(phenyl) phosphane-κP]palladium(II), [PdCl2{P(C6H11)2(C6H 5)}2] [Burgoyne et al. (2012). Acta Cryst. E68, m404].",

keywords = "R factor = 0.061, T = 100 K, data-to-parameter ratio = 22.7, mean{\= }(C-C) = 0.008 {\AA}, single-crystal X-ray study, wR factor = 0.165",

author = "Isaac Buthelezi and Haleden Chiririwa and Hezron Ogutu and Reinout Meijboom",

year = "2012",

month = nov,

doi = "10.1107/S1600536812040810",

language = "English",

volume = "68",

pages = "m1330--m1331",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

}

TY - JOUR

T1 - Trans-Dichloridobis[dicyclohexyl(2,4,6-trimethylphenyl)phosphane-κP] palladium(II)

AU - Buthelezi, Isaac

AU - Chiririwa, Haleden

AU - Ogutu, Hezron

AU - Meijboom, Reinout

PY - 2012/11

Y1 - 2012/11

N2 - The title compound, [PdCl2(C21H33P)2], forms a monomeric complex with a trans-square-planar coordination geometry about the PdII atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760(13)Å, while the Pd-Cl bond lengths are 2.3172(14)Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclohexyl(phenyl) phosphane-κP]palladium(II), [PdCl2{P(C6H11)2(C6H 5)}2] [Burgoyne et al. (2012). Acta Cryst. E68, m404].

AB - The title compound, [PdCl2(C21H33P)2], forms a monomeric complex with a trans-square-planar coordination geometry about the PdII atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760(13)Å, while the Pd-Cl bond lengths are 2.3172(14)Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclohexyl(phenyl) phosphane-κP]palladium(II), [PdCl2{P(C6H11)2(C6H 5)}2] [Burgoyne et al. (2012). Acta Cryst. E68, m404].

KW - R factor = 0.061

KW - T = 100 K

KW - data-to-parameter ratio = 22.7

KW - mean ̄(C-C) = 0.008 Å

KW - single-crystal X-ray study

KW - wR factor = 0.165

UR - http://www.scopus.com/inward/record.url?scp=84870914146&partnerID=8YFLogxK

U2 - 10.1107/S1600536812040810

DO - 10.1107/S1600536812040810

M3 - Article

AN - SCOPUS:84870914146

SN - 1600-5368

VL - 68

SP - m1330-m1331

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-Dichloridobis[dicyclohexyl(2,4,6-trimethylphenyl)phosphane-κP] palladium(II)

Abstract

Keywords

ASJC Scopus subject areas

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