Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane} palladium(II)

Alfred Muller; Reinout Meijboom

doi:10.1107/S1600536810042595

Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane} palladium(II)

Alfred Muller, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The title compound, trans-[PdCl₂{PPh₂(4-Me ₂NC₆H₄)}₂], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl ₂P₂ square-planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C - H⋯Cl hydrogen bonds also occur.

Original language	English
Pages (from-to)	m1463
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S1600536810042595
Publication status	Published - Nov 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane} palladium(II)",

abstract = "The title compound, trans-[PdCl2{PPh2(4-Me 2NC6H4)}2], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl 2P2 square-planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3550 (7) and 2.2906 (7) {\AA}, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) {\AA}. Intra- and intermolecular C - H⋯Cl hydrogen bonds also occur.",

author = "Alfred Muller and Reinout Meijboom",

year = "2010",

month = nov,

doi = "10.1107/S1600536810042595",

language = "English",

volume = "66",

pages = "m1463",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

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T1 - Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane} palladium(II)

AU - Muller, Alfred

AU - Meijboom, Reinout

PY - 2010/11

Y1 - 2010/11

N2 - The title compound, trans-[PdCl2{PPh2(4-Me 2NC6H4)}2], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl 2P2 square-planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C - H⋯Cl hydrogen bonds also occur.

AB - The title compound, trans-[PdCl2{PPh2(4-Me 2NC6H4)}2], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl 2P2 square-planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C - H⋯Cl hydrogen bonds also occur.

UR - http://www.scopus.com/inward/record.url?scp=78650927060&partnerID=8YFLogxK

U2 - 10.1107/S1600536810042595

DO - 10.1107/S1600536810042595

M3 - Article

AN - SCOPUS:78650927060

SN - 1600-5368

VL - 66

SP - m1463

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane} palladium(II)

Abstract

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