Trans-dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate

Alfred Muller; Reinout Meijboom

doi:10.1107/S1600536810040912

Trans-dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate

Alfred Muller, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the title compound, trans-[PdCl₂{P(4-MeOC₆H ₄)₃}₂]·C₇H₈, the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C - H⋯Cl hydrogen bond occurs. In the crystal, weak C - H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.

Original language	English
Pages (from-to)	m1420
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S1600536810040912
Publication status	Published - Nov 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate",

abstract = "In the title compound, trans-[PdCl2{P(4-MeOC6H 4)3}2]·C7H8, the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3409 (4) and 2.2981 (4) {\AA}, respectively. An intra-molecular C - H⋯Cl hydrogen bond occurs. In the crystal, weak C - H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.",

author = "Alfred Muller and Reinout Meijboom",

year = "2010",

month = nov,

doi = "10.1107/S1600536810040912",

language = "English",

volume = "66",

pages = "m1420",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

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T1 - Trans-dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate

AU - Muller, Alfred

AU - Meijboom, Reinout

PY - 2010/11

Y1 - 2010/11

N2 - In the title compound, trans-[PdCl2{P(4-MeOC6H 4)3}2]·C7H8, the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C - H⋯Cl hydrogen bond occurs. In the crystal, weak C - H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.

AB - In the title compound, trans-[PdCl2{P(4-MeOC6H 4)3}2]·C7H8, the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd - P and Pd - Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C - H⋯Cl hydrogen bond occurs. In the crystal, weak C - H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.

UR - http://www.scopus.com/inward/record.url?scp=78650933424&partnerID=8YFLogxK

U2 - 10.1107/S1600536810040912

DO - 10.1107/S1600536810040912

M3 - Article

AN - SCOPUS:78650933424

SN - 1600-5368

VL - 66

SP - m1420

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate

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