Trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine]rhodium(I)

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536805017447

Trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine]rhodium(I)

Reinout Meijboom, Alfred Muller, Andreas Roodt

University of The Free State

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The title compound, trans-[RhCl(C₁₈F₁₅P) ₂(CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 (14) and 2.2993 (14) Å, Rh-Cl = 2.3642 (12) Å, Rh-C = 1.824 (4) Å, C-Rh-Cl = 174.12(13)° P-Rh-C = 91.73(13) and 93.71(13)°, P-Rh-P = 169.38(4)° and Rh-C≡O = 176.7 (4)°. The effective cone angles (θ_E) for the phosphine ligands were calculated to be 172 and 173°.

Original language	English
Pages (from-to)	m1283-m1285
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	7
DOIs	https://doi.org/10.1107/S1600536805017447
Publication status	Published - 1 Jul 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{69e643822a36493b947f147a65b434a9,

title = "Trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine]rhodium(I)",

abstract = "The title compound, trans-[RhCl(C18F15P) 2(CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 (14) and 2.2993 (14) {\AA}, Rh-Cl = 2.3642 (12) {\AA}, Rh-C = 1.824 (4) {\AA}, C-Rh-Cl = 174.12(13)° P-Rh-C = 91.73(13) and 93.71(13)°, P-Rh-P = 169.38(4)° and Rh-C≡O = 176.7 (4)°. The effective cone angles (θE) for the phosphine ligands were calculated to be 172 and 173°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2005",

month = jul,

day = "1",

doi = "10.1107/S1600536805017447",

language = "English",

volume = "61",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine]rhodium(I)

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2005/7/1

Y1 - 2005/7/1

N2 - The title compound, trans-[RhCl(C18F15P) 2(CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 (14) and 2.2993 (14) Å, Rh-Cl = 2.3642 (12) Å, Rh-C = 1.824 (4) Å, C-Rh-Cl = 174.12(13)° P-Rh-C = 91.73(13) and 93.71(13)°, P-Rh-P = 169.38(4)° and Rh-C≡O = 176.7 (4)°. The effective cone angles (θE) for the phosphine ligands were calculated to be 172 and 173°.

AB - The title compound, trans-[RhCl(C18F15P) 2(CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 (14) and 2.2993 (14) Å, Rh-Cl = 2.3642 (12) Å, Rh-C = 1.824 (4) Å, C-Rh-Cl = 174.12(13)° P-Rh-C = 91.73(13) and 93.71(13)°, P-Rh-P = 169.38(4)° and Rh-C≡O = 176.7 (4)°. The effective cone angles (θE) for the phosphine ligands were calculated to be 172 and 173°.

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U2 - 10.1107/S1600536805017447

DO - 10.1107/S1600536805017447

M3 - Article

AN - SCOPUS:32244441858

SN - 1600-5368

VL - 61

SP - m1283-m1285

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine]rhodium(I)

Abstract

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