Trans-Carbonylchlorobis[tris(2,6-dimethyl-phenyl)phosphito]rhodium(I)

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536804006270

Trans-Carbonylchlorobis[tris(2,6-dimethyl-phenyl)phosphito]rhodium(I)

Reinout Meijboom, Alfred Muller, Andreas Roodt

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The title compound, [RhCl{P(OC₈H₉)₃} ₂(CO)], where P(OC₈H₉)₃ is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1-P1 and Rh2-P2 bond distances are 2.3097 (7) and 2.2995 (7) Å, respectively. The effective cone angle for the phosphite ligands was calculated as 182°.

Original language	English
Pages (from-to)	m455-m457
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	4
DOIs	https://doi.org/10.1107/S1600536804006270
Publication status	Published - Apr 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-Carbonylchlorobis[tris(2,6-dimethyl-phenyl)phosphito]rhodium(I)",

abstract = "The title compound, [RhCl{P(OC8H9)3} 2(CO)], where P(OC8H9)3 is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1-P1 and Rh2-P2 bond distances are 2.3097 (7) and 2.2995 (7) {\AA}, respectively. The effective cone angle for the phosphite ligands was calculated as 182°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2004",

month = apr,

doi = "10.1107/S1600536804006270",

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volume = "60",

pages = "m455--m457",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Trans-Carbonylchlorobis[tris(2,6-dimethyl-phenyl)phosphito]rhodium(I)

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2004/4

Y1 - 2004/4

N2 - The title compound, [RhCl{P(OC8H9)3} 2(CO)], where P(OC8H9)3 is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1-P1 and Rh2-P2 bond distances are 2.3097 (7) and 2.2995 (7) Å, respectively. The effective cone angle for the phosphite ligands was calculated as 182°.

AB - The title compound, [RhCl{P(OC8H9)3} 2(CO)], where P(OC8H9)3 is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1-P1 and Rh2-P2 bond distances are 2.3097 (7) and 2.2995 (7) Å, respectively. The effective cone angle for the phosphite ligands was calculated as 182°.

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U2 - 10.1107/S1600536804006270

DO - 10.1107/S1600536804006270

M3 - Article

AN - SCOPUS:18444383366

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VL - 60

SP - m455-m457

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Trans-Carbonylchlorobis[tris(2,6-dimethyl-phenyl)phosphito]rhodium(I)

Abstract

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