Trans-Carbonylchlorobis[tris(2-methylphenyl)phosphito]rhodium(I)

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536804015594

Trans-Carbonylchlorobis[tris(2-methylphenyl)phosphito]rhodium(I)

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The title compound, [Rh{P(OC₇H₇)₃} ₂Cl(CO)], where P(OC₇H₇)₃ is tris(2-methylphenyl)phosphite, crystallizes disordered over an inversion centre. Important geometrical parameters are Rh-P = 2.2905 (9) Å, Rh-Cl = 2.402 (4) Å, Rh-C = 1.764 (10) Å, and C-Rh-Cl = 177.7 (5)°, P-Rh-Cl = 85.84 (12)° and Rh-C=O = 174.7 (15)°. The effective cone angle for the phosphite ligand was calculated to be 167°.

Original language	English
Pages (from-to)	m1071-m1073
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804015594
Publication status	Published - Aug 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{0870b153e14b4f7ba39344e44a0d3864,

title = "Trans-Carbonylchlorobis[tris(2-methylphenyl)phosphito]rhodium(I)",

abstract = "The title compound, [Rh\{P(OC7H7)3\} 2Cl(CO)], where P(OC7H7)3 is tris(2-methylphenyl)phosphite, crystallizes disordered over an inversion centre. Important geometrical parameters are Rh-P = 2.2905 (9) {\AA}, Rh-Cl = 2.402 (4) {\AA}, Rh-C = 1.764 (10) {\AA}, and C-Rh-Cl = 177.7 (5)°, P-Rh-Cl = 85.84 (12)° and Rh-C=O = 174.7 (15)°. The effective cone angle for the phosphite ligand was calculated to be 167°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2004",

month = aug,

doi = "10.1107/S1600536804015594",

language = "English",

volume = "60",

pages = "m1071--m1073",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Trans-Carbonylchlorobis[tris(2-methylphenyl)phosphito]rhodium(I)

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2004/8

Y1 - 2004/8

N2 - The title compound, [Rh{P(OC7H7)3} 2Cl(CO)], where P(OC7H7)3 is tris(2-methylphenyl)phosphite, crystallizes disordered over an inversion centre. Important geometrical parameters are Rh-P = 2.2905 (9) Å, Rh-Cl = 2.402 (4) Å, Rh-C = 1.764 (10) Å, and C-Rh-Cl = 177.7 (5)°, P-Rh-Cl = 85.84 (12)° and Rh-C=O = 174.7 (15)°. The effective cone angle for the phosphite ligand was calculated to be 167°.

AB - The title compound, [Rh{P(OC7H7)3} 2Cl(CO)], where P(OC7H7)3 is tris(2-methylphenyl)phosphite, crystallizes disordered over an inversion centre. Important geometrical parameters are Rh-P = 2.2905 (9) Å, Rh-Cl = 2.402 (4) Å, Rh-C = 1.764 (10) Å, and C-Rh-Cl = 177.7 (5)°, P-Rh-Cl = 85.84 (12)° and Rh-C=O = 174.7 (15)°. The effective cone angle for the phosphite ligand was calculated to be 167°.

UR - https://www.scopus.com/pages/publications/18444365308

U2 - 10.1107/S1600536804015594

DO - 10.1107/S1600536804015594

M3 - Article

AN - SCOPUS:18444365308

SN - 1600-5368

VL - 60

SP - m1071-m1073

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Trans-Carbonylchlorobis[tris(2-methylphenyl)phosphito]rhodium(I)

Abstract

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