Trans-carbonylchlorobis(tri-m-tolylphosphino)-rhodium(I) dichloromethane solvate

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536805005738

Trans-carbonylchlorobis(tri-m-tolylphosphino)-rhodium(I) dichloromethane solvate

Reinout Meijboom, Alfred Muller, Andreas Roodt

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [RhCl(P(C₇H₇).,) ₂(CO)]·CH₂C]₂, where P(C ₇H₇)₃ is tri-m-tolylphosphine, crystallizes with a dichloromethane molecule in the asymmetric unit. Important geometrical parameters are Rh-P = 2.3229 (15) and 2.3269 (15) Å, Rh-Cl = 2.3659 (15) A. Rh-C = 1.793 (6) Å, C-Rh-Cl = 174.6(2)°, P-Rh-C = 90.33 (17)° and 92.68 (17)°, and Rh-C=O = 176.2 (5)°. The effective cone angles for the phosphine ligands were calculated to be 160 and 155°.

Original language	English
Pages (from-to)	m699-m701
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S1600536805005738
Publication status	Published - Apr 2005

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{80963cb393974eb7b40fe522051fc7e8,

title = "Trans-carbonylchlorobis(tri-m-tolylphosphino)-rhodium(I) dichloromethane solvate",

abstract = "The title compound, [RhCl(P(C7H7).,) 2(CO)]·CH2C]2, where P(C 7H7)3 is tri-m-tolylphosphine, crystallizes with a dichloromethane molecule in the asymmetric unit. Important geometrical parameters are Rh-P = 2.3229 (15) and 2.3269 (15) {\AA}, Rh-Cl = 2.3659 (15) A. Rh-C = 1.793 (6) {\AA}, C-Rh-Cl = 174.6(2)°, P-Rh-C = 90.33 (17)° and 92.68 (17)°, and Rh-C=O = 176.2 (5)°. The effective cone angles for the phosphine ligands were calculated to be 160 and 155°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2005",

month = apr,

doi = "10.1107/S1600536805005738",

language = "English",

volume = "61",

pages = "m699--m701",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - Trans-carbonylchlorobis(tri-m-tolylphosphino)-rhodium(I) dichloromethane solvate

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2005/4

Y1 - 2005/4

N2 - The title compound, [RhCl(P(C7H7).,) 2(CO)]·CH2C]2, where P(C 7H7)3 is tri-m-tolylphosphine, crystallizes with a dichloromethane molecule in the asymmetric unit. Important geometrical parameters are Rh-P = 2.3229 (15) and 2.3269 (15) Å, Rh-Cl = 2.3659 (15) A. Rh-C = 1.793 (6) Å, C-Rh-Cl = 174.6(2)°, P-Rh-C = 90.33 (17)° and 92.68 (17)°, and Rh-C=O = 176.2 (5)°. The effective cone angles for the phosphine ligands were calculated to be 160 and 155°.

AB - The title compound, [RhCl(P(C7H7).,) 2(CO)]·CH2C]2, where P(C 7H7)3 is tri-m-tolylphosphine, crystallizes with a dichloromethane molecule in the asymmetric unit. Important geometrical parameters are Rh-P = 2.3229 (15) and 2.3269 (15) Å, Rh-Cl = 2.3659 (15) A. Rh-C = 1.793 (6) Å, C-Rh-Cl = 174.6(2)°, P-Rh-C = 90.33 (17)° and 92.68 (17)°, and Rh-C=O = 176.2 (5)°. The effective cone angles for the phosphine ligands were calculated to be 160 and 155°.

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U2 - 10.1107/S1600536805005738

DO - 10.1107/S1600536805005738

M3 - Article

AN - SCOPUS:18544363146

SN - 1600-5368

VL - 61

SP - m699-m701

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Trans-carbonylchlorobis(tri-m-tolylphosphino)-rhodium(I) dichloromethane solvate

Abstract

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