Trans-Carbonylchloridobis[tris(naph-thalen-1-yl)-phosphane-kP]rhodium(I) acetone trisolvate

Reinout Meijboom

doi:10.1107/S1600536811038505

Trans-Carbonylchloridobis[tris(naph-thalen-1-yl)-phosphane-kP]rhodium(I) acetone trisolvate

Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title compound, trans-[RhCl{P(C ₁₀H ₇) ₃} ₂(CO)]·3C ₃H ₆O, where P(C ₁₀H ₇) ₃ is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

Original language	English
Pages (from-to)	m1438
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	10
DOIs	https://doi.org/10.1107/S1600536811038505
Publication status	Published - Oct 2011

Keywords

R factor = 0.046
T = 100 K
data-to-parameter ratio = 19.6
mean σ(C-C) = 0.006 Å
single-crystal X-ray study
wR factor = 0.098

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536811038505

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title = "Trans-Carbonylchloridobis[tris(naph-thalen-1-yl)-phosphane-kP]rhodium(I) acetone trisolvate",

abstract = "In the title compound, trans-[RhCl{P(C 10H 7) 3} 2(CO)]·3C 3H 6O, where P(C 10H 7) 3 is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) {\AA}, while the Rh-Cl bond length is 2.3525 (11) {\AA}. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.",

keywords = "R factor = 0.046, T = 100 K, data-to-parameter ratio = 19.6, mean σ(C-C) = 0.006 {\AA}, single-crystal X-ray study, wR factor = 0.098",

author = "Reinout Meijboom",

year = "2011",

month = oct,

doi = "10.1107/S1600536811038505",

language = "English",

volume = "67",

pages = "m1438",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

}

TY - JOUR

T1 - Trans-Carbonylchloridobis[tris(naph-thalen-1-yl)-phosphane-kP]rhodium(I) acetone trisolvate

AU - Meijboom, Reinout

PY - 2011/10

Y1 - 2011/10

N2 - In the title compound, trans-[RhCl{P(C 10H 7) 3} 2(CO)]·3C 3H 6O, where P(C 10H 7) 3 is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

AB - In the title compound, trans-[RhCl{P(C 10H 7) 3} 2(CO)]·3C 3H 6O, where P(C 10H 7) 3 is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

KW - R factor = 0.046

KW - T = 100 K

KW - data-to-parameter ratio = 19.6

KW - mean σ(C-C) = 0.006 Å

KW - single-crystal X-ray study

KW - wR factor = 0.098

UR - http://www.scopus.com/inward/record.url?scp=80055019437&partnerID=8YFLogxK

U2 - 10.1107/S1600536811038505

DO - 10.1107/S1600536811038505

M3 - Article

AN - SCOPUS:80055019437

SN - 1600-5368

VL - 67

SP - m1438

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Trans-Carbonylchloridobis[tris(naph-thalen-1-yl)-phosphane-kP]rhodium(I) acetone trisolvate

Abstract

Keywords

ASJC Scopus subject areas

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