Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate

Andrew R. Burgoyne; Reinout Meijboom; Alfred Muller; Bernard O. Omondi

doi:10.1107/S1600536810039814

Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate

Andrew R. Burgoyne, Reinout Meijboom, Alfred Muller, Bernard O. Omondi

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, trans-[RhCl(C₁₈H₁₂Cl ₃P)₂(CO)]·C₃H₆O, contains an Rh(I) atom in a distorted square-planar coordination with a P - Rh - P angle of 175.27 (2)° and Rh - P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl - Rh unit results in a reduced P - Rh - Cl angle of 86.675 (15)°.

Original language	English
Pages (from-to)	m1380-m1381
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S1600536810039814
Publication status	Published - Nov 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{182d256b7aa347bf8b4b81086e61e01a,

title = "Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate",

abstract = "The title compound, trans-[RhCl(C18H12Cl 3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P - Rh - P angle of 175.27 (2)° and Rh - P bond lengths of 2.3127 (4) and 2.3219 (4) {\AA}. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl - Rh unit results in a reduced P - Rh - Cl angle of 86.675 (15)°.",

author = "Burgoyne, {Andrew R.} and Reinout Meijboom and Alfred Muller and Omondi, {Bernard O.}",

year = "2010",

month = nov,

doi = "10.1107/S1600536810039814",

language = "English",

volume = "66",

pages = "m1380--m1381",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate

AU - Burgoyne, Andrew R.

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Omondi, Bernard O.

PY - 2010/11

Y1 - 2010/11

N2 - The title compound, trans-[RhCl(C18H12Cl 3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P - Rh - P angle of 175.27 (2)° and Rh - P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl - Rh unit results in a reduced P - Rh - Cl angle of 86.675 (15)°.

AB - The title compound, trans-[RhCl(C18H12Cl 3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P - Rh - P angle of 175.27 (2)° and Rh - P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl - Rh unit results in a reduced P - Rh - Cl angle of 86.675 (15)°.

UR - http://www.scopus.com/inward/record.url?scp=78650963758&partnerID=8YFLogxK

U2 - 10.1107/S1600536810039814

DO - 10.1107/S1600536810039814

M3 - Article

AN - SCOPUS:78650963758

SN - 1600-5368

VL - 66

SP - m1380-m1381

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate

Abstract

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