Trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-κP] dichloridopalladium(II)

Charmaine Van Blerk; Cedric W. Holzapfel

doi:10.1107/S1600536809040744

Trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-κP] dichloridopalladium(II)

Charmaine Van Blerk, Cedric W. Holzapfel

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The structure of the title compound, [PdCl₂(C₂₀H ₁₉O₂P)₂], shows a square-planar geometry for the Pd^II ion within a Cl₂Pd[PPh(PhOMe)2]2 ligand set. The Pd^II atom sits on an inversion centre and therefore the asymmetric unit contains the Pd^II atom, one Cl atom and one bis-(2-methoxy-phen- yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.

Original language	English
Pages (from-to)	m1341
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	11
DOIs	https://doi.org/10.1107/S1600536809040744
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "The structure of the title compound, [PdCl2(C20H 19O2P)2], shows a square-planar geometry for the PdII ion within a Cl2Pd[PPh(PhOMe)2]2 ligand set. The PdII atom sits on an inversion centre and therefore the asymmetric unit contains the PdII atom, one Cl atom and one bis-(2-methoxy-phen- yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.",

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AB - The structure of the title compound, [PdCl2(C20H 19O2P)2], shows a square-planar geometry for the PdII ion within a Cl2Pd[PPh(PhOMe)2]2 ligand set. The PdII atom sits on an inversion centre and therefore the asymmetric unit contains the PdII atom, one Cl atom and one bis-(2-methoxy-phen- yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.

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Trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-κP] dichloridopalladium(II)

Abstract

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