Trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)

Alfred Muller

doi:10.1107/S160053681204696X

Trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)

Alfred Muller

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt^II atom is occupied by two benzyldiphenylphosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl interactions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.

Original language	English
Pages (from-to)	m1512
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S160053681204696X
Publication status	Published - Dec 2012

Keywords

R factor = 0.018
T = 100 K
data-to-parameter ratio = 21.3
mean ω(C-C) = 0.003 Å
single-crystal X-ray study
wR factor = 0.039

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S160053681204696X

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title = "Trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)",

abstract = "In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the PtII atom is occupied by two benzyldiphenylphosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl interactions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) {\AA} and ring slippage = 2.386 {\AA}] are observed.",

keywords = "R factor = 0.018, T = 100 K, data-to-parameter ratio = 21.3, mean ω(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.039",

author = "Alfred Muller",

year = "2012",

month = dec,

doi = "10.1107/S160053681204696X",

language = "English",

volume = "68",

pages = "m1512",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)

AU - Muller, Alfred

PY - 2012/12

Y1 - 2012/12

N2 - In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the PtII atom is occupied by two benzyldiphenylphosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl interactions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.

AB - In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the PtII atom is occupied by two benzyldiphenylphosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl interactions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.

KW - R factor = 0.018

KW - T = 100 K

KW - data-to-parameter ratio = 21.3

KW - mean ω(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.039

UR - http://www.scopus.com/inward/record.url?scp=84870860136&partnerID=8YFLogxK

U2 - 10.1107/S160053681204696X

DO - 10.1107/S160053681204696X

M3 - Article

AN - SCOPUS:84870860136

SN - 1600-5368

VL - 68

SP - m1512

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)

Abstract

Keywords

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