Trans-Bis[3,5-bis(trifluoromethyl)-1Hpyrazole-κN2] dichloropalladium(II) monohydrate

Lara C. Spencer; Ilia A. Guzei; Stephen O. Ojwach; James Darkwa

doi:10.1107/S0108270106025030

Trans-Bis[3,5-bis(trifluoromethyl)-1Hpyrazole-κN²] dichloropalladium(II) monohydrate

Lara C. Spencer
, Ilia A. Guzei
, Stephen O. Ojwach
, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The palladium(II) center in the title compound, trans-[PdCl ₂(C₅H₂F₆N₂) ₂]·H₂O, possesses a distorted square-planar geometry. The NH groups are positioned on the same side of the PdN ₂Cl₂ coordination plane. Four symmetry-independent strong hydrogen bonds of three types (N-H⋯Cl, NH⋯Cl and O-H⋯Cl) hold the structure together.

Original language	English
Pages (from-to)	m421-m423
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	9
DOIs	https://doi.org/10.1107/S0108270106025030
Publication status	Published - Sept 2006

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "Trans-Bis[3,5-bis(trifluoromethyl)-1Hpyrazole-κN2] dichloropalladium(II) monohydrate",

abstract = "The palladium(II) center in the title compound, trans-[PdCl 2(C5H2F6N2) 2]·H2O, possesses a distorted square-planar geometry. The NH groups are positioned on the same side of the PdN 2Cl2 coordination plane. Four symmetry-independent strong hydrogen bonds of three types (N-H⋯Cl, NH⋯Cl and O-H⋯Cl) hold the structure together.",

author = "Spencer, \{Lara C.\} and Guzei, \{Ilia A.\} and Ojwach, \{Stephen O.\} and James Darkwa",

year = "2006",

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language = "English",

volume = "62",

pages = "m421--m423",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "9",

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T1 - Trans-Bis[3,5-bis(trifluoromethyl)-1Hpyrazole-κN2] dichloropalladium(II) monohydrate

AU - Spencer, Lara C.

AU - Guzei, Ilia A.

AU - Ojwach, Stephen O.

AU - Darkwa, James

PY - 2006/9

Y1 - 2006/9

N2 - The palladium(II) center in the title compound, trans-[PdCl 2(C5H2F6N2) 2]·H2O, possesses a distorted square-planar geometry. The NH groups are positioned on the same side of the PdN 2Cl2 coordination plane. Four symmetry-independent strong hydrogen bonds of three types (N-H⋯Cl, NH⋯Cl and O-H⋯Cl) hold the structure together.

AB - The palladium(II) center in the title compound, trans-[PdCl 2(C5H2F6N2) 2]·H2O, possesses a distorted square-planar geometry. The NH groups are positioned on the same side of the PdN 2Cl2 coordination plane. Four symmetry-independent strong hydrogen bonds of three types (N-H⋯Cl, NH⋯Cl and O-H⋯Cl) hold the structure together.

UR - https://www.scopus.com/pages/publications/33748791458

U2 - 10.1107/S0108270106025030

DO - 10.1107/S0108270106025030

M3 - Article

AN - SCOPUS:33748791458

SN - 0108-2701

VL - 62

SP - m421-m423

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

Trans-Bis[3,5-bis(trifluoromethyl)-1Hpyrazole-κN²] dichloropalladium(II) monohydrate

Abstract

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