Trans-Bis[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-chlorido- rhodium(I)

Frederick P. Malan; Rehana Malgas-Enus; Reinout Meijboom

doi:10.1107/S1600536812012421

Trans-Bis[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-chlorido- rhodium(I)

Frederick P. Malan, Rehana Malgas-Enus, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, trans-[RhCl(C ₁₈H ₁₄BrP) ₂(CO)], has a slightly disordered square-planar geometry with the Rh ion ^I situated on an inversion the centre and carbon-yl-chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh-P = 2.3430 (8) Å, Rh-Cl = 2.434 (3) Å, Rh-C = 1.722 (8) Å, P-Rh-P = 180.00 (3)°, P-Rh-Cl = 95.40 (7)°, 84.60 (7)° and Rh-C-O = 177.9 (8)°.

Original language	English
Pages (from-to)	m510
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	4
DOIs	https://doi.org/10.1107/S1600536812012421
Publication status	Published - Apr 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{07e8cfa227674c7ab433636a1cd9524e,

title = "Trans-Bis[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-chlorido- rhodium(I)",

abstract = "The title compound, trans-[RhCl(C 18H 14BrP) 2(CO)], has a slightly disordered square-planar geometry with the Rh ion I situated on an inversion the centre and carbon-yl-chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh-P = 2.3430 (8) {\AA}, Rh-Cl = 2.434 (3) {\AA}, Rh-C = 1.722 (8) {\AA}, P-Rh-P = 180.00 (3)°, P-Rh-Cl = 95.40 (7)°, 84.60 (7)° and Rh-C-O = 177.9 (8)°.",

author = "Malan, {Frederick P.} and Rehana Malgas-Enus and Reinout Meijboom",

year = "2012",

month = apr,

doi = "10.1107/S1600536812012421",

language = "English",

volume = "68",

pages = "m510",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

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T1 - Trans-Bis[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-chlorido- rhodium(I)

AU - Malan, Frederick P.

AU - Malgas-Enus, Rehana

AU - Meijboom, Reinout

PY - 2012/4

Y1 - 2012/4

N2 - The title compound, trans-[RhCl(C 18H 14BrP) 2(CO)], has a slightly disordered square-planar geometry with the Rh ion I situated on an inversion the centre and carbon-yl-chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh-P = 2.3430 (8) Å, Rh-Cl = 2.434 (3) Å, Rh-C = 1.722 (8) Å, P-Rh-P = 180.00 (3)°, P-Rh-Cl = 95.40 (7)°, 84.60 (7)° and Rh-C-O = 177.9 (8)°.

AB - The title compound, trans-[RhCl(C 18H 14BrP) 2(CO)], has a slightly disordered square-planar geometry with the Rh ion I situated on an inversion the centre and carbon-yl-chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh-P = 2.3430 (8) Å, Rh-Cl = 2.434 (3) Å, Rh-C = 1.722 (8) Å, P-Rh-P = 180.00 (3)°, P-Rh-Cl = 95.40 (7)°, 84.60 (7)° and Rh-C-O = 177.9 (8)°.

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U2 - 10.1107/S1600536812012421

DO - 10.1107/S1600536812012421

M3 - Article

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SN - 1600-5368

VL - 68

SP - m510

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Trans-Bis[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-chlorido- rhodium(I)

Abstract

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