Time-dependent perturbed angular distribution studies of chemical-vapour-deposited diamond

E. Sideras-Haddad; S. H. Connell; J. P.F. Sellschop; M. C. Stemmet; K. Bharuth-Ram

doi:10.1016/0925-9635(94)90048-5

Time-dependent perturbed angular distribution studies of chemical-vapour-deposited diamond

E. Sideras-Haddad, S. H. Connell, J. P.F. Sellschop, M. C. Stemmet, K. Bharuth-Ram

Research output: Contribution to journal › Article › peer-review

Abstract

The time differential perturbed angular distribution technique has been applied to studies in synthetic diamond grown by the chemical vapor deposition method. It was found that the ¹⁹F nuclear probe used occupies only one characteristic lattice site associated with a coupling frequency of 63(3) MHz. This result represents a starkly different situation when compared with previous findings from extensive investigations on three different types of natural diamond, as well as on synthetic diamond grown under high temperature, high pressure conditions. Such comparison has revealed the role of hydrogen in the different types of diamond and its particular chemical form of occurrence. As hydrogen seems to play an important role in different methods of synthesis, these findings give a first insight into such synthesis aspects.

Original language	English
Pages (from-to)	151-154
Number of pages	4
Journal	Diamond and Related Materials
Volume	3
Issue number	1-2
DOIs	https://doi.org/10.1016/0925-9635(94)90048-5
Publication status	Published - Jan 1994
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Mechanical Engineering
Materials Chemistry
Electrical and Electronic Engineering

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10.1016/0925-9635(94)90048-5

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title = "Time-dependent perturbed angular distribution studies of chemical-vapour-deposited diamond",

abstract = "The time differential perturbed angular distribution technique has been applied to studies in synthetic diamond grown by the chemical vapor deposition method. It was found that the 19F nuclear probe used occupies only one characteristic lattice site associated with a coupling frequency of 63(3) MHz. This result represents a starkly different situation when compared with previous findings from extensive investigations on three different types of natural diamond, as well as on synthetic diamond grown under high temperature, high pressure conditions. Such comparison has revealed the role of hydrogen in the different types of diamond and its particular chemical form of occurrence. As hydrogen seems to play an important role in different methods of synthesis, these findings give a first insight into such synthesis aspects.",

author = "E. Sideras-Haddad and Connell, {S. H.} and Sellschop, {J. P.F.} and Stemmet, {M. C.} and K. Bharuth-Ram",

year = "1994",

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doi = "10.1016/0925-9635(94)90048-5",

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AU - Sideras-Haddad, E.

AU - Connell, S. H.

AU - Sellschop, J. P.F.

AU - Stemmet, M. C.

AU - Bharuth-Ram, K.

PY - 1994/1

Y1 - 1994/1

N2 - The time differential perturbed angular distribution technique has been applied to studies in synthetic diamond grown by the chemical vapor deposition method. It was found that the 19F nuclear probe used occupies only one characteristic lattice site associated with a coupling frequency of 63(3) MHz. This result represents a starkly different situation when compared with previous findings from extensive investigations on three different types of natural diamond, as well as on synthetic diamond grown under high temperature, high pressure conditions. Such comparison has revealed the role of hydrogen in the different types of diamond and its particular chemical form of occurrence. As hydrogen seems to play an important role in different methods of synthesis, these findings give a first insight into such synthesis aspects.

AB - The time differential perturbed angular distribution technique has been applied to studies in synthetic diamond grown by the chemical vapor deposition method. It was found that the 19F nuclear probe used occupies only one characteristic lattice site associated with a coupling frequency of 63(3) MHz. This result represents a starkly different situation when compared with previous findings from extensive investigations on three different types of natural diamond, as well as on synthetic diamond grown under high temperature, high pressure conditions. Such comparison has revealed the role of hydrogen in the different types of diamond and its particular chemical form of occurrence. As hydrogen seems to play an important role in different methods of synthesis, these findings give a first insight into such synthesis aspects.

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JO - Diamond and Related Materials

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IS - 1-2

ER -

Time-dependent perturbed angular distribution studies of chemical-vapour-deposited diamond

Abstract

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