Thermal properties and nonisothermal crystallization behaviour of polypropylene nanocomposite

Jayita Bandyopadhyay, Raphaale Mekoa, Sifiso Skosana, Suprakas Sinha Ray

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

Nucleated polypropylene (PP) masterbatch and the nanoclay-containing composite of PP are prepared by reactive processing method to improve the thermo-mechanical properties of virgin PP. PP masterbatch and the nanocomposite exhibits pronounced improvement in crystallization temperature (Tc) and the heat distortion temperature (HDT) when compared with neat PP. The melting and nonisothermal crystallization behaviors of the neat PP and the nanocomposite are studied by differential scanning calorimetry. Results indicate that half time of crystallization at a particular cooling rate remains unchanged in neat PP and the nanocomposite. However, super cooling effect is pronounced in the nanocomposite when compared with neat PP. Irrespective of cooling rate there is approximately 14% improvement in Tc in PP nanocomposite with respect the neat PP. Such an improvement in Tc with improved thermo-mechanical properties are highly desirable for rigid packaging applications.

Original languageEnglish
Title of host publicationProceedings of PPS2019, Europe-Africa Regional Conference of the Polymer Processing Society
EditorsSuprakas Sinha Ray
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735440197
DOIs
Publication statusPublished - 26 Nov 2020
EventPPS Europe-Africa 2019 Regional Conference, PPS 2019 - Pretoria, South Africa
Duration: 18 Nov 201922 Nov 2019

Publication series

NameAIP Conference Proceedings
Volume2289
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

ConferencePPS Europe-Africa 2019 Regional Conference, PPS 2019
Country/TerritorySouth Africa
CityPretoria
Period18/11/1922/11/19

ASJC Scopus subject areas

  • General Physics and Astronomy

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