The magmatic and magmatic-hydrothermal evolution of felsic igneous rocks as seen through Nb-Ta geochemical fractionation, with implications for the origins of rare-metal mineralizations

Christophe Ballouard, Malcolm Massuyeau, Marlina A. Elburg, Sebastian Tappe, Fanus Viljoen, Jean Tristan Brandenburg

Research output: Contribution to journalReview articlepeer-review

85 Citations (Scopus)

Abstract

Despite Nb and Ta being considered as ‘geochemical twins’, most Ta mineral deposits are associated with muscovite-bearing peraluminous granites and related pegmatites (MPG), whereas significant Nb deposits are related to peralkaline to metaluminous A1-type granites and syenites as well as nepheline syenites. Metaluminous to peraluminous A2-type granites and syenites have a lower potential for rare-metal mineralization. The Nb/Ta ratios are highly variable within each type of rare-metal-enriched felsic igneous suite and causes of the Nb-Ta geochemical fractionation remain poorly understood. Our compilation of whole-rock geochemical data indicates that Nb/Ta ratios generally anticorrelate with Ta, and at given Ta contents the Nb/Ta ratios increase from MPG through A2-type to A1-type igneous suites. However, the Nb-Ta compositions of A1-type and silica-undersaturated felsic magmatic rocks are indistinguishable. New regression models to estimate the mineral/melt partition coefficients DNb and DTa indicate that fractional crystallization of biotite and ilmenite significantly decreases Nb/Ta, but an extreme degree of fractional crystallization is needed to explain the observed range of Nb-Ta variations in rare-metal-enriched igneous suites. Importantly, metasomatic rocks formed by the alteration of igneous suites and their country-rocks are commonly highly enriched in Ta and Nb. Their low Nb/Ta ratios suggest that magmatic-hydrothermal processes involving fluids and hydrosaline melts also play a critical role in Nb-Ta geochemical fractionation and HFSE enrichment in general. We show that the Nb-Ta compositions of the primitive end-members of rare-metal-enriched felsic igneous suites fingerprint the nature and evolution of their sources including metasomatic processes in the Earth's crust and upper mantle.

Original languageEnglish
Article number103115
JournalEarth-Science Reviews
Volume203
DOIs
Publication statusPublished - Apr 2020

Keywords

  • A-type and peraluminous granites
  • Fractional crystallization
  • Magmatic-hydrothermal transition
  • Mineral/melt partition coefficients
  • Niobium and tantalum
  • Peralkaline complexes

ASJC Scopus subject areas

  • General Earth and Planetary Sciences

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