The homoleptic sandwich anion [Co(P2C2tBu 2)2]-: A versatile building block for phosphaorganometallic chemistry

Robert Wolf; Andreas W. Ehlers; J. Chris Slootweg; Martin Lutz; Dietrich Gudat; Michael Hunger; Anthony L. Spek; Koop Lammertsma

doi:10.1002/anie.200800813

The homoleptic sandwich anion [Co(P₂C₂tBu ₂)₂]^-: A versatile building block for phosphaorganometallic chemistry

Robert Wolf, Andreas W. Ehlers, J. Chris Slootweg, Martin Lutz, Dietrich Gudat, Michael Hunger, Anthony L. Spek, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

(Chemical Equation Presented) A sandwich recipe: Treatment of the anthracene complex [Co(η⁴-C₁₄H₁₀) ₂]^- with tBuC≡P leads to the new diphosphacyclobutadiene sandwich anion 1, which can be converted into the unprecedented phosphaorganometallic complexes 2-4 upon treatment with different electrophiles (see scheme).

Original language	English
Pages (from-to)	4584-4587
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	24
DOIs	https://doi.org/10.1002/anie.200800813
Publication status	Published - 2 Jun 2008
Externally published	Yes

Keywords

Cobalt
Density functional calculations
Hydrides
Phosphorus
Sandwich complexes

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200800813

Cite this

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abstract = "(Chemical Equation Presented) A sandwich recipe: Treatment of the anthracene complex [Co(η4-C14H10) 2]- with tBuC≡P leads to the new diphosphacyclobutadiene sandwich anion 1, which can be converted into the unprecedented phosphaorganometallic complexes 2-4 upon treatment with different electrophiles (see scheme).",

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AU - Wolf, Robert

AU - Ehlers, Andreas W.

AU - Slootweg, J. Chris

AU - Lutz, Martin

AU - Gudat, Dietrich

AU - Hunger, Michael

AU - Spek, Anthony L.

AU - Lammertsma, Koop

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AB - (Chemical Equation Presented) A sandwich recipe: Treatment of the anthracene complex [Co(η4-C14H10) 2]- with tBuC≡P leads to the new diphosphacyclobutadiene sandwich anion 1, which can be converted into the unprecedented phosphaorganometallic complexes 2-4 upon treatment with different electrophiles (see scheme).

KW - Cobalt

KW - Density functional calculations

KW - Hydrides

KW - Phosphorus

KW - Sandwich complexes

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