The Geochemistry of Archean shales derived from a mafic volcanic sequence, Belingwe greenstone belt, Zimbabwe: Provenance, source area unroofing and submarine versus subaerial weathering

Shales of Ο2.7 Ga Zeederbergs Formation, Belingwe greenstone belt, Zimbabwe, form thin (0.2-2 m) horizons intercalated with submarine lava plain basalts. Shales of the overlying Cheshire Formation, a foreland basin sedimentary sequence, form 1-100 m thick units intercalated with shallow-water carbonates and deep-water, resedimented basalt pebble conglomerates. Zeederbergs shale is characterized by high contents of MgO and transition metals and low concentrations of K₂O and LILE as compared to average Phanerozoic shale, indicative of an ultramafic to mafic source terrain. Cheshire shales have similar major and trace element contents, but M_gO and transition metals are less enriched and the LILE are less depleted. Zeederbergs shales have smoothly fractionated REE patterns (La_N/Yb_N = 2.84-4.45) and no significant Eu anomaly (Eu/Eu*= 0.93- 0.96). REE patterns are identical to those of the surrounding basaltic rocks, indicating local derivation from submarine reworking. Cheshire shales have rather flat REE patterns (La_N/Yb_N = 0.69 -2.19) and a small, negative Eu anomaly (average Eu/Eu*= 0.85), indicative of a mafic provenance with minor contributions of felsic detritus. A systematic change in REE patterns and concentrations of transition metals and HFSE upwards in the sedimentary succession indicates erosion of progressively more LREE-depleted basalts and ultramafic volcanic rocks, followed by unroofing of granitoid crust. Weathering indices confirm the submarine nature of Zeederbergs shale, whereas Cheshire shale was derived from a source terrain subjected to intense chemical weathering.