Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

Reinout Meijboom; J. Marthinus Janse Van Rensburg; Leo Kirsten; J. Augustinus Viljoen

doi:10.1107/S1600536806036373

Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

Reinout Meijboom, J. Marthinus Janse Van Rensburg, Leo Kirsten, J. Augustinus Viljoen

University of The Free State

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, [Ag(AsC₁₈H₁₅)₄]PF ₆, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry 3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) Å, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)°.

Original language	English
Pages (from-to)	m2567-m2569
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	10
DOIs	https://doi.org/10.1107/S1600536806036373
Publication status	Published - Oct 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Tetrakis(triphenylarsine)silver(I) hexafluorophosphate",

abstract = "The title compound, [Ag(AsC18H15)4]PF 6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry 3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) {\AA}, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)°.",

author = "Reinout Meijboom and {Van Rensburg}, {J. Marthinus Janse} and Leo Kirsten and Viljoen, {J. Augustinus}",

year = "2006",

month = oct,

doi = "10.1107/S1600536806036373",

language = "English",

volume = "62",

pages = "m2567--m2569",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

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T1 - Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

AU - Meijboom, Reinout

AU - Van Rensburg, J. Marthinus Janse

AU - Kirsten, Leo

AU - Viljoen, J. Augustinus

PY - 2006/10

Y1 - 2006/10

N2 - The title compound, [Ag(AsC18H15)4]PF 6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry 3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) Å, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)°.

AB - The title compound, [Ag(AsC18H15)4]PF 6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry 3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) Å, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)°.

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U2 - 10.1107/S1600536806036373

DO - 10.1107/S1600536806036373

M3 - Article

AN - SCOPUS:33750010934

SN - 1600-5368

VL - 62

SP - m2567-m2569

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

Abstract

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