Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate

Gertruida J.S. Venter, Reinout Meijboom, Andreas Roodt

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The title compound, [Ag(P(p-tol)3}4]PF6 or [Ag(C21H21P)4]-PF6, crystallizes with parts of two independent formula units in the asymmetric unit. The Ag-P distances range between 2.5665(13) and 2.6142 (7) Å, and the P-Ag-P angles between 109.310 (18) and 109.632 (18)°, indicating a distorted tetrahedral geometry. Both Ag atoms and both PF6- anions lie on threefold rotation axes.

Original languageEnglish
Pages (from-to)m3453-m3455
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number12
DOIs
Publication statusPublished - Dec 2006
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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