Tetra-μ-acetato-κ 8 O:O′-bis-[(3,5-dimethyl-1H- pyrazole-κN 2)-copper(II)]

Juanita Van Wyk, Bernard Omondi, James Darkwa

Research output: Contribution to journalArticlepeer-review

Abstract

The dinuclear centrosymmetric title compound, [Cu 2(CH 3CO 2) 4(C 5H 8N 2) 2], has a distorted squarepyramidal coordination geometry around each Cu II atom in which four O atoms from the bridging acetate ligands form the basal plane while two N atoms from the pyrazole ligands occupy the apical positions. The crystal has two half molecules in the asymmetric unit with a Cu⋯Cu distance of 2.6762 (4) Å. Disorder was found for two O atoms and two C atoms of one acetate ligand and refined with occupancies of 0.265 (7) and 0.735 (7). The crystal also features molecules linked through two N - H⋯O hydrogen bonds resulting in onedimensional chains extending along the crystallographic b axis.

Original languageEnglish
Pages (from-to)m1299
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number9
DOIs
Publication statusPublished - Sept 2011

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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