Abstract
The dinuclear centrosymmetric title compound, [Cu 2(CH 3CO 2) 4(C 5H 8N 2) 2], has a distorted squarepyramidal coordination geometry around each Cu II atom in which four O atoms from the bridging acetate ligands form the basal plane while two N atoms from the pyrazole ligands occupy the apical positions. The crystal has two half molecules in the asymmetric unit with a Cu⋯Cu distance of 2.6762 (4) Å. Disorder was found for two O atoms and two C atoms of one acetate ligand and refined with occupancies of 0.265 (7) and 0.735 (7). The crystal also features molecules linked through two N - H⋯O hydrogen bonds resulting in onedimensional chains extending along the crystallographic b axis.
Original language | English |
---|---|
Pages (from-to) | m1299 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 67 |
Issue number | 9 |
DOIs | |
Publication status | Published - Sept 2011 |
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics