Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Helen Jansen; Florian B. Läng; J. C. Slootweg; Andreas W. Ehlers; Martin Lutz; Koop Lammertsma; Hansjörg Grützmacher

doi:10.1002/anie.201000901

Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Helen Jansen
, Florian B. Läng
, J. C. Slootweg
, Andreas W. Ehlers
, Martin Lutz
, Koop Lammertsma
, Hansjörg Grützmacher

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Chargedl Combining ^MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

Original language	English
Pages (from-to)	5485-5488
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	32
DOIs	https://doi.org/10.1002/anie.201000901
Publication status	Published - 26 Jul 2010
Externally published	Yes

Keywords

Carbenes
Cations
Heterocycles
Phosphiranes
Phosphorus

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201000901

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abstract = "Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)",

keywords = "Carbenes, Cations, Heterocycles, Phosphiranes, Phosphorus",

author = "Helen Jansen and L{\"a}ng, \{Florian B.\} and Slootweg, \{J. C.\} and Ehlers, \{Andreas W.\} and Martin Lutz and Koop Lammertsma and Hansj{\"o}rg Gr{\"u}tzmacher",

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T1 - Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

AU - Jansen, Helen

AU - Läng, Florian B.

AU - Slootweg, J. C.

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Lammertsma, Koop

AU - Grützmacher, Hansjörg

PY - 2010/7/26

Y1 - 2010/7/26

N2 - Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

AB - Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

KW - Carbenes

KW - Cations

KW - Heterocycles

KW - Phosphiranes

KW - Phosphorus

UR - https://www.scopus.com/pages/publications/77955036990

U2 - 10.1002/anie.201000901

DO - 10.1002/anie.201000901

M3 - Article

C2 - 20602378

AN - SCOPUS:77955036990

SN - 1433-7851

VL - 49

SP - 5485

EP - 5488

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Abstract

Keywords

ASJC Scopus subject areas

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