Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Helen Jansen; Florian B. Läng; J. C. Slootweg; Andreas W. Ehlers; Martin Lutz; Koop Lammertsma; Hansjörg Grützmacher

doi:10.1002/anie.201000901

Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Helen Jansen, Florian B. Läng, J. C. Slootweg, Andreas W. Ehlers, Martin Lutz, Koop Lammertsma, Hansjörg Grützmacher

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Chargedl Combining ^MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

Original language	English
Pages (from-to)	5485-5488
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	32
DOIs	https://doi.org/10.1002/anie.201000901
Publication status	Published - 26 Jul 2010
Externally published	Yes

Keywords

Carbenes
Cations
Heterocycles
Phosphiranes
Phosphorus

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201000901

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abstract = "Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)",

keywords = "Carbenes, Cations, Heterocycles, Phosphiranes, Phosphorus",

author = "Helen Jansen and L{\"a}ng, {Florian B.} and Slootweg, {J. C.} and Ehlers, {Andreas W.} and Martin Lutz and Koop Lammertsma and Hansj{\"o}rg Gr{\"u}tzmacher",

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T1 - Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

AU - Jansen, Helen

AU - Läng, Florian B.

AU - Slootweg, J. C.

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Lammertsma, Koop

AU - Grützmacher, Hansjörg

PY - 2010/7/26

Y1 - 2010/7/26

N2 - Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

AB - Chargedl Combining MeBABAR-Phos and methyl triflate affords an amino-stabilized phosphiranylium ion (see picture; C. gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P-substituted phosphiranes and an N-heterocyclic carbene stabilized phosphiranylium cation. (Figure Presented)

KW - Carbenes

KW - Cations

KW - Heterocycles

KW - Phosphiranes

KW - Phosphorus

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U2 - 10.1002/anie.201000901

DO - 10.1002/anie.201000901

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

Abstract

Keywords

ASJC Scopus subject areas

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