Synthesis of quinoline based heterocyclic compounds for blue lighting application

Vinod Kumar; Mukut Gohain; Johannes H. Van Tonder; S. Ponra; B. C.B. Bezuindenhoudt; O. M. Ntwaeaborwa; H. C. Swart

doi:10.1016/j.optmat.2015.11.009

Synthesis of quinoline based heterocyclic compounds for blue lighting application

Vinod Kumar, Mukut Gohain, Johannes H. Van Tonder, S. Ponra, B. C.B. Bezuindenhoudt, O. M. Ntwaeaborwa, H. C. Swart

University of The Free State

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

2,4-Diphenylquinoline (DPQ), derivatives 6-chloro-2,4-diphenylquinoline (DPQ-Cl) and 4′,6-dichloro-2,4-diphenylquinoline (DPQ-Cl₂) were synthesized using a three-component domino reaction. The DPQ, DPQ-Cl and DPQ-Cl₂ were characterized by nuclear magnetic resonance spectroscopy, scanning electron microscopy, thermogravimetric analysis (TGA). Fourier transformed infra-red spectroscopy, X-ray photoelectron spectroscopy (XPS), Ultraviolet-visible (UV-vis) spectroscopy and photoluminescence spectroscopy. The TGA results showed that the DPQ was more thermally stable with respect to the DPQ-Cl and DPQ-Cl₂. The synthesized organic phosphors showed bright emission in the blue region under an UV excitation wavelength of 325 nm with the power of 18 mW. These organic phosphors were found to be efficient candidate and may be used in organic blue light emitting devices.

Original language	English
Pages (from-to)	275-281
Number of pages	7
Journal	Optical Materials
Volume	50
DOIs	https://doi.org/10.1016/j.optmat.2015.11.009
Publication status	Published - Dec 2015
Externally published	Yes

Keywords

Blue emission
Diphenylquinoline
NMR
XPS

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Computer Science
Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrical and Electronic Engineering

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10.1016/j.optmat.2015.11.009

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@article{5ba112f49f4646388db1334a7c18f05d,

title = "Synthesis of quinoline based heterocyclic compounds for blue lighting application",

abstract = "2,4-Diphenylquinoline (DPQ), derivatives 6-chloro-2,4-diphenylquinoline (DPQ-Cl) and 4′,6-dichloro-2,4-diphenylquinoline (DPQ-Cl2) were synthesized using a three-component domino reaction. The DPQ, DPQ-Cl and DPQ-Cl2 were characterized by nuclear magnetic resonance spectroscopy, scanning electron microscopy, thermogravimetric analysis (TGA). Fourier transformed infra-red spectroscopy, X-ray photoelectron spectroscopy (XPS), Ultraviolet-visible (UV-vis) spectroscopy and photoluminescence spectroscopy. The TGA results showed that the DPQ was more thermally stable with respect to the DPQ-Cl and DPQ-Cl2. The synthesized organic phosphors showed bright emission in the blue region under an UV excitation wavelength of 325 nm with the power of 18 mW. These organic phosphors were found to be efficient candidate and may be used in organic blue light emitting devices.",

keywords = "Blue emission, Diphenylquinoline, NMR, XPS",

author = "Vinod Kumar and Mukut Gohain and {Van Tonder}, {Johannes H.} and S. Ponra and Bezuindenhoudt, {B. C.B.} and Ntwaeaborwa, {O. M.} and Swart, {H. C.}",

year = "2015",

month = dec,

doi = "10.1016/j.optmat.2015.11.009",

language = "English",

volume = "50",

pages = "275--281",

journal = "Optical Materials",

issn = "0925-3467",

publisher = "Elsevier",

}

TY - JOUR

T1 - Synthesis of quinoline based heterocyclic compounds for blue lighting application

AU - Kumar, Vinod

AU - Gohain, Mukut

AU - Van Tonder, Johannes H.

AU - Ponra, S.

AU - Bezuindenhoudt, B. C.B.

AU - Ntwaeaborwa, O. M.

AU - Swart, H. C.

PY - 2015/12

Y1 - 2015/12

N2 - 2,4-Diphenylquinoline (DPQ), derivatives 6-chloro-2,4-diphenylquinoline (DPQ-Cl) and 4′,6-dichloro-2,4-diphenylquinoline (DPQ-Cl2) were synthesized using a three-component domino reaction. The DPQ, DPQ-Cl and DPQ-Cl2 were characterized by nuclear magnetic resonance spectroscopy, scanning electron microscopy, thermogravimetric analysis (TGA). Fourier transformed infra-red spectroscopy, X-ray photoelectron spectroscopy (XPS), Ultraviolet-visible (UV-vis) spectroscopy and photoluminescence spectroscopy. The TGA results showed that the DPQ was more thermally stable with respect to the DPQ-Cl and DPQ-Cl2. The synthesized organic phosphors showed bright emission in the blue region under an UV excitation wavelength of 325 nm with the power of 18 mW. These organic phosphors were found to be efficient candidate and may be used in organic blue light emitting devices.

AB - 2,4-Diphenylquinoline (DPQ), derivatives 6-chloro-2,4-diphenylquinoline (DPQ-Cl) and 4′,6-dichloro-2,4-diphenylquinoline (DPQ-Cl2) were synthesized using a three-component domino reaction. The DPQ, DPQ-Cl and DPQ-Cl2 were characterized by nuclear magnetic resonance spectroscopy, scanning electron microscopy, thermogravimetric analysis (TGA). Fourier transformed infra-red spectroscopy, X-ray photoelectron spectroscopy (XPS), Ultraviolet-visible (UV-vis) spectroscopy and photoluminescence spectroscopy. The TGA results showed that the DPQ was more thermally stable with respect to the DPQ-Cl and DPQ-Cl2. The synthesized organic phosphors showed bright emission in the blue region under an UV excitation wavelength of 325 nm with the power of 18 mW. These organic phosphors were found to be efficient candidate and may be used in organic blue light emitting devices.

KW - Blue emission

KW - Diphenylquinoline

KW - NMR

KW - XPS

UR - http://www.scopus.com/inward/record.url?scp=84947750931&partnerID=8YFLogxK

U2 - 10.1016/j.optmat.2015.11.009

DO - 10.1016/j.optmat.2015.11.009

M3 - Article

AN - SCOPUS:84947750931

SN - 0925-3467

VL - 50

SP - 275

EP - 281

JO - Optical Materials

JF - Optical Materials

ER -

Synthesis of quinoline based heterocyclic compounds for blue lighting application

Abstract

Keywords

ASJC Scopus subject areas

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