Synthesis of phosphine stabilised group 11 1-azaallyl complexes; molecular structure of bu3iPAuCH(R)C(but) = NR (R = SiMe3)

Richard J. Bowen; Judy Caddy; Manuel A. Fernandes; Marcus Layh; Messai A. Mamo

doi:10.1016/j.poly.2004.07.008

Synthesis of phosphine stabilised group 11 1-azaallyl complexes; molecular structure of bu₃ⁱPAuCH(R)C(bu^t) = NR (R = SiMe₃)

Richard J. Bowen
, Judy Caddy
, Manuel A. Fernandes
, Marcus Layh
, Messai A. Mamo

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The bonding mode (η¹-enamide for Cu; η¹- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu₃ⁱPM[N(R)C(bu^t)=C(H)R] (M = Cu, Ag, Au; R = SiMe₃), synthesised from bu₃ⁱPMCl (M = Cu, Ag, Au) and [Li{μ-N(R)C(bu^t)C(H)R}]₂ (R = SiMe ₃), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.

Original language	English
Pages (from-to)	2273-2280
Number of pages	8
Journal	Polyhedron
Volume	23
Issue number	14
DOIs	https://doi.org/10.1016/j.poly.2004.07.008
Publication status	Published - 9 Sept 2004
Externally published	Yes

Keywords

1-azaallyls
Group 11 phosphine complexes
Iminoalkyl bonding mode
X-ray crystallography

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2004.07.008

Cite this

@article{a2295940b9f84df5a4b9d9dd96545d70,

title = "Synthesis of phosphine stabilised group 11 1-azaallyl complexes; molecular structure of bu3iPAuCH(R)C(but) = NR (R = SiMe3)",

abstract = "The bonding mode (η1-enamide for Cu; η1- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu3iPM[N(R)C(but)=C(H)R] (M = Cu, Ag, Au; R = SiMe3), synthesised from bu3iPMCl (M = Cu, Ag, Au) and [Li\{μ-N(R)C(but)C(H)R\}]2 (R = SiMe 3), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.",

keywords = "1-azaallyls, Group 11 phosphine complexes, Iminoalkyl bonding mode, X-ray crystallography",

author = "Bowen, \{Richard J.\} and Judy Caddy and Fernandes, \{Manuel A.\} and Marcus Layh and Mamo, \{Messai A.\}",

year = "2004",

month = sep,

day = "9",

doi = "10.1016/j.poly.2004.07.008",

language = "English",

volume = "23",

pages = "2273--2280",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "14",

}

TY - JOUR

T1 - Synthesis of phosphine stabilised group 11 1-azaallyl complexes; molecular structure of bu3iPAuCH(R)C(but) = NR (R = SiMe3)

AU - Bowen, Richard J.

AU - Caddy, Judy

AU - Fernandes, Manuel A.

AU - Layh, Marcus

AU - Mamo, Messai A.

PY - 2004/9/9

Y1 - 2004/9/9

N2 - The bonding mode (η1-enamide for Cu; η1- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu3iPM[N(R)C(but)=C(H)R] (M = Cu, Ag, Au; R = SiMe3), synthesised from bu3iPMCl (M = Cu, Ag, Au) and [Li{μ-N(R)C(but)C(H)R}]2 (R = SiMe 3), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.

AB - The bonding mode (η1-enamide for Cu; η1- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu3iPM[N(R)C(but)=C(H)R] (M = Cu, Ag, Au; R = SiMe3), synthesised from bu3iPMCl (M = Cu, Ag, Au) and [Li{μ-N(R)C(but)C(H)R}]2 (R = SiMe 3), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.

KW - 1-azaallyls

KW - Group 11 phosphine complexes

KW - Iminoalkyl bonding mode

KW - X-ray crystallography

UR - https://www.scopus.com/pages/publications/4444366949

U2 - 10.1016/j.poly.2004.07.008

DO - 10.1016/j.poly.2004.07.008

M3 - Article

AN - SCOPUS:4444366949

SN - 0277-5387

VL - 23

SP - 2273

EP - 2280

JO - Polyhedron

JF - Polyhedron

IS - 14

ER -