Abstract
The bonding mode (η1-enamide for Cu; η1- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu3iPM[N(R)C(but)=C(H)R] (M = Cu, Ag, Au; R = SiMe3), synthesised from bu3iPMCl (M = Cu, Ag, Au) and [Li{μ-N(R)C(but)C(H)R}]2 (R = SiMe 3), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.
Original language | English |
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Pages (from-to) | 2273-2280 |
Number of pages | 8 |
Journal | Polyhedron |
Volume | 23 |
Issue number | 14 |
DOIs | |
Publication status | Published - 9 Sept 2004 |
Externally published | Yes |
Keywords
- 1-azaallyls
- Group 11 phosphine complexes
- Iminoalkyl bonding mode
- X-ray crystallography
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry