Synthesis of phosphine stabilised group 11 1-azaallyl complexes; molecular structure of bu3iPAuCH(R)C(but) = NR (R = SiMe3)

Richard J. Bowen, Judy Caddy, Manuel A. Fernandes, Marcus Layh, Messai A. Mamo

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The bonding mode (η1-enamide for Cu; η1- iminoalkyl for Ag, Au) of the linear, two-coordinate 1-azaallyl complexes bu3iPM[N(R)C(but)=C(H)R] (M = Cu, Ag, Au; R = SiMe3), synthesised from bu3iPMCl (M = Cu, Ag, Au) and [Li{μ-N(R)C(but)C(H)R}]2 (R = SiMe 3), was determined by NMR spectroscopy and in the case of the Au-derivative by X-ray crystallography.

Original languageEnglish
Pages (from-to)2273-2280
Number of pages8
JournalPolyhedron
Volume23
Issue number14
DOIs
Publication statusPublished - 9 Sept 2004
Externally publishedYes

Keywords

  • 1-azaallyls
  • Group 11 phosphine complexes
  • Iminoalkyl bonding mode
  • X-ray crystallography

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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