Synthesis and Coordination Chemistry of Iminophosphanes

Tom Vandijk; Sebastian Burck; Amos J. Rosenthal; Martin Nieger; Andreas W. Ehlers; J. Chris Slootweg; Koop Lammertsma

doi:10.1002/chem.201501126

Synthesis and Coordination Chemistry of Iminophosphanes

Tom Vandijk, Sebastian Burck, Amos J. Rosenthal, Martin Nieger, Andreas W. Ehlers, J. Chris Slootweg, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Iminophosphanes are a new group of 1,3-P,N-ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N-donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes. Know what imino? Iminophosphanes are a new group of tunable 1,3-P,N-ligands, readily obtained from secondary phosphanes and nitrilium ions. They produce, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes.

Original language	English
Pages (from-to)	9328-9331
Number of pages	4
Journal	Chemistry - A European Journal
Volume	21
Issue number	26
DOIs	https://doi.org/10.1002/chem.201501126
Publication status	Published - 1 Jun 2015
Externally published	Yes

Keywords

N P ligands
coordination modes
density functional calculations
ligand design
synthetic methods

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201501126

Cite this

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title = "Synthesis and Coordination Chemistry of Iminophosphanes",

abstract = "Iminophosphanes are a new group of 1,3-P,N-ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N-donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes. Know what imino? Iminophosphanes are a new group of tunable 1,3-P,N-ligands, readily obtained from secondary phosphanes and nitrilium ions. They produce, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes.",

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author = "Tom Vandijk and Sebastian Burck and Rosenthal, {Amos J.} and Martin Nieger and Ehlers, {Andreas W.} and Slootweg, {J. Chris} and Koop Lammertsma",

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doi = "10.1002/chem.201501126",

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T1 - Synthesis and Coordination Chemistry of Iminophosphanes

AU - Vandijk, Tom

AU - Burck, Sebastian

AU - Rosenthal, Amos J.

AU - Nieger, Martin

AU - Ehlers, Andreas W.

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

PY - 2015/6/1

Y1 - 2015/6/1

N2 - Iminophosphanes are a new group of 1,3-P,N-ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N-donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes. Know what imino? Iminophosphanes are a new group of tunable 1,3-P,N-ligands, readily obtained from secondary phosphanes and nitrilium ions. They produce, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes.

AB - Iminophosphanes are a new group of 1,3-P,N-ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N-donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes. Know what imino? Iminophosphanes are a new group of tunable 1,3-P,N-ligands, readily obtained from secondary phosphanes and nitrilium ions. They produce, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes.

KW - N P ligands

KW - coordination modes

KW - density functional calculations

KW - ligand design

KW - synthetic methods

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DO - 10.1002/chem.201501126

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JO - Chemistry - A European Journal

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Synthesis and Coordination Chemistry of Iminophosphanes

Abstract

Keywords

ASJC Scopus subject areas

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