Synthesis and characterization of lithiated dendrimers

Reinout Meijboom; Alan T. Hutton; John R. Moss

doi:10.1021/om020799i

Synthesis and characterization of lithiated dendrimers

Reinout Meijboom, Alan T. Hutton, John R. Moss

University of Cape Town

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The synthesis of the precursor phenylthiomethyl-functionalized carbosilane dendrimers Si[(CH₂)₃SiMe₂CH₂SPh]₄ (1) and Si{(CH₂)₃Si[(CH₂)₃SiMe₂ CH₂SPh]₃}₄ (2) is described. Reacting 1 and 2 with lithium naphthalenide gives the first lithiomethyl-functionalized dendrimers Si[(CH₂)₃SiMe₂CH₂Li]₄ (7) and Si{(CH₂)₃Si[(CH₂)₃ SiMe₂CH₂Li]₃}₄ (11). Deutero, trimethylsilyl, trimethylstannyl, and tri-n-butylstannyl derivatives of these dendrimers, as well as a method to enable isolation of the lithiated dendrimers as solids, are described.

Original language	English
Pages (from-to)	1811-1815
Number of pages	5
Journal	Organometallics
Volume	22
Issue number	9
DOIs	https://doi.org/10.1021/om020799i
Publication status	Published - 28 Apr 2003
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and characterization of lithiated dendrimers",

abstract = "The synthesis of the precursor phenylthiomethyl-functionalized carbosilane dendrimers Si[(CH2)3SiMe2CH2SPh]4 (1) and Si\{(CH2)3Si[(CH2)3SiMe2 CH2SPh]3\}4 (2) is described. Reacting 1 and 2 with lithium naphthalenide gives the first lithiomethyl-functionalized dendrimers Si[(CH2)3SiMe2CH2Li]4 (7) and Si\{(CH2)3Si[(CH2)3 SiMe2CH2Li]3\}4 (11). Deutero, trimethylsilyl, trimethylstannyl, and tri-n-butylstannyl derivatives of these dendrimers, as well as a method to enable isolation of the lithiated dendrimers as solids, are described.",

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T1 - Synthesis and characterization of lithiated dendrimers

AU - Meijboom, Reinout

AU - Hutton, Alan T.

AU - Moss, John R.

PY - 2003/4/28

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N2 - The synthesis of the precursor phenylthiomethyl-functionalized carbosilane dendrimers Si[(CH2)3SiMe2CH2SPh]4 (1) and Si{(CH2)3Si[(CH2)3SiMe2 CH2SPh]3}4 (2) is described. Reacting 1 and 2 with lithium naphthalenide gives the first lithiomethyl-functionalized dendrimers Si[(CH2)3SiMe2CH2Li]4 (7) and Si{(CH2)3Si[(CH2)3 SiMe2CH2Li]3}4 (11). Deutero, trimethylsilyl, trimethylstannyl, and tri-n-butylstannyl derivatives of these dendrimers, as well as a method to enable isolation of the lithiated dendrimers as solids, are described.

AB - The synthesis of the precursor phenylthiomethyl-functionalized carbosilane dendrimers Si[(CH2)3SiMe2CH2SPh]4 (1) and Si{(CH2)3Si[(CH2)3SiMe2 CH2SPh]3}4 (2) is described. Reacting 1 and 2 with lithium naphthalenide gives the first lithiomethyl-functionalized dendrimers Si[(CH2)3SiMe2CH2Li]4 (7) and Si{(CH2)3Si[(CH2)3 SiMe2CH2Li]3}4 (11). Deutero, trimethylsilyl, trimethylstannyl, and tri-n-butylstannyl derivatives of these dendrimers, as well as a method to enable isolation of the lithiated dendrimers as solids, are described.

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DO - 10.1021/om020799i

M3 - Article

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SP - 1811

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JO - Organometallics

JF - Organometallics

IS - 9

ER -

Synthesis and characterization of lithiated dendrimers

Abstract

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