Synthesis and characterization of an unusual equatorially substituted di-manganese compound. The first structural determination of a phosphite compound of type [Mn2(CO)9P]

Reinout Meijboom; Phibion Dhirori; Ipe J. Mavunkal

doi:10.1016/j.ica.2008.04.039

Synthesis and characterization of an unusual equatorially substituted di-manganese compound. The first structural determination of a phosphite compound of type [Mn₂(CO)₉P]

Reinout Meijboom, Phibion Dhirori, Ipe J. Mavunkal

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Reaction of (acetonitrile)-nona(carbonyl)-di-manganese and tri-iso-propyl phosphite provided the new phosphite compound [Mn₂(CO)₉L]. The product was fully characterized and the molecular structure was determined by single crystal X-ray diffraction. This represents the first structural analysis of a di-manganese carbonyl compound containing phosphite ligands. In addition, this compound displays a rare example of an equatorially substituted di-manganese carbonyl compound.

Original language	English
Pages (from-to)	617-620
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	362
Issue number	2
DOIs	https://doi.org/10.1016/j.ica.2008.04.039
Publication status	Published - 20 Jan 2009
Externally published	Yes

Keywords

Manganese
Phosphite
X-ray crystallography

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2008.04.039

Cite this

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abstract = "Reaction of (acetonitrile)-nona(carbonyl)-di-manganese and tri-iso-propyl phosphite provided the new phosphite compound [Mn2(CO)9L]. The product was fully characterized and the molecular structure was determined by single crystal X-ray diffraction. This represents the first structural analysis of a di-manganese carbonyl compound containing phosphite ligands. In addition, this compound displays a rare example of an equatorially substituted di-manganese carbonyl compound.",

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T1 - Synthesis and characterization of an unusual equatorially substituted di-manganese compound. The first structural determination of a phosphite compound of type [Mn2(CO)9P]

AU - Meijboom, Reinout

AU - Dhirori, Phibion

AU - Mavunkal, Ipe J.

PY - 2009/1/20

Y1 - 2009/1/20

N2 - Reaction of (acetonitrile)-nona(carbonyl)-di-manganese and tri-iso-propyl phosphite provided the new phosphite compound [Mn2(CO)9L]. The product was fully characterized and the molecular structure was determined by single crystal X-ray diffraction. This represents the first structural analysis of a di-manganese carbonyl compound containing phosphite ligands. In addition, this compound displays a rare example of an equatorially substituted di-manganese carbonyl compound.

AB - Reaction of (acetonitrile)-nona(carbonyl)-di-manganese and tri-iso-propyl phosphite provided the new phosphite compound [Mn2(CO)9L]. The product was fully characterized and the molecular structure was determined by single crystal X-ray diffraction. This represents the first structural analysis of a di-manganese carbonyl compound containing phosphite ligands. In addition, this compound displays a rare example of an equatorially substituted di-manganese carbonyl compound.

KW - Manganese

KW - Phosphite

KW - X-ray crystallography

UR - http://www.scopus.com/inward/record.url?scp=57749098890&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2008.04.039

DO - 10.1016/j.ica.2008.04.039

M3 - Article

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SN - 0020-1693

VL - 362

SP - 617

EP - 620

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -