Synthesis and characterisation of dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts

Richard J. Bowen; Judy Caddy; Manuel A. Fernandes; Marcus Layh; Messai A. Mamo; Reinout Meijboom

doi:10.1016/j.jorganchem.2005.10.005

Synthesis and characterisation of dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts

Richard J. Bowen, Judy Caddy, Manuel A. Fernandes, Marcus Layh, Messai A. Mamo, Reinout Meijboom

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The novel dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts (R ₂Sn)(O,O′-dpmaa) [1a, R = Me; 1b, R = Bu; dpmaa = bis(diphenylphosphino)maleic acid] were synthesised from dpmaa and R ₂SnCl₂ or Bu₂SnO. They were fully characterised by elemental analysis, IR- and multinuclear NMR-spectroscopies as well as X-ray crystallography [in the case of 1a as its Ph ₂P(O)(CH₂)₂P(O)Ph₂ adduct]. Both were found to be cyclic trimers in the solid state that dissolve in the case of 1b into an equilibrium mixture of oligomers.

Original language	English
Pages (from-to)	717-725
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	4
DOIs	https://doi.org/10.1016/j.jorganchem.2005.10.005
Publication status	Published - 1 Feb 2006
Externally published	Yes

Keywords

2,3-Bis(diphenylphosphino)maleic acid adducts
Cyclic trimer
Dialkyltin carboxylates
X-ray

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2005.10.005

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title = "Synthesis and characterisation of dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts",

abstract = "The novel dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts (R 2Sn)(O,O′-dpmaa) [1a, R = Me; 1b, R = Bu; dpmaa = bis(diphenylphosphino)maleic acid] were synthesised from dpmaa and R 2SnCl2 or Bu2SnO. They were fully characterised by elemental analysis, IR- and multinuclear NMR-spectroscopies as well as X-ray crystallography [in the case of 1a as its Ph 2P(O)(CH2)2P(O)Ph2 adduct]. Both were found to be cyclic trimers in the solid state that dissolve in the case of 1b into an equilibrium mixture of oligomers.",

keywords = "2,3-Bis(diphenylphosphino)maleic acid adducts, Cyclic trimer, Dialkyltin carboxylates, X-ray",

author = "Bowen, {Richard J.} and Judy Caddy and Fernandes, {Manuel A.} and Marcus Layh and Mamo, {Messai A.} and Reinout Meijboom",

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doi = "10.1016/j.jorganchem.2005.10.005",

language = "English",

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T1 - Synthesis and characterisation of dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts

AU - Bowen, Richard J.

AU - Caddy, Judy

AU - Fernandes, Manuel A.

AU - Layh, Marcus

AU - Mamo, Messai A.

AU - Meijboom, Reinout

PY - 2006/2/1

Y1 - 2006/2/1

N2 - The novel dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts (R 2Sn)(O,O′-dpmaa) [1a, R = Me; 1b, R = Bu; dpmaa = bis(diphenylphosphino)maleic acid] were synthesised from dpmaa and R 2SnCl2 or Bu2SnO. They were fully characterised by elemental analysis, IR- and multinuclear NMR-spectroscopies as well as X-ray crystallography [in the case of 1a as its Ph 2P(O)(CH2)2P(O)Ph2 adduct]. Both were found to be cyclic trimers in the solid state that dissolve in the case of 1b into an equilibrium mixture of oligomers.

AB - The novel dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts (R 2Sn)(O,O′-dpmaa) [1a, R = Me; 1b, R = Bu; dpmaa = bis(diphenylphosphino)maleic acid] were synthesised from dpmaa and R 2SnCl2 or Bu2SnO. They were fully characterised by elemental analysis, IR- and multinuclear NMR-spectroscopies as well as X-ray crystallography [in the case of 1a as its Ph 2P(O)(CH2)2P(O)Ph2 adduct]. Both were found to be cyclic trimers in the solid state that dissolve in the case of 1b into an equilibrium mixture of oligomers.

KW - 2,3-Bis(diphenylphosphino)maleic acid adducts

KW - Cyclic trimer

KW - Dialkyltin carboxylates

KW - X-ray

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U2 - 10.1016/j.jorganchem.2005.10.005

DO - 10.1016/j.jorganchem.2005.10.005

M3 - Article

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SN - 0022-328X

VL - 691

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JF - Journal of Organometallic Chemistry

IS - 4

ER -

Synthesis and characterisation of dialkyltin 2,3-bis(diphenylphosphino)maleic acid adducts

Abstract

Keywords

ASJC Scopus subject areas

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