Synthesis and analytical characterization of Ca-BTC metal organic framework

Munazza Ramzan; Malika Rani; Rabia Siddiqui; Aqeel Ahmad Shah; Maryam Arshad; Muhammad Wasif Ghauri; Ghazanfar Abbas; Kareem Yusuf; Mika Sillanpää

doi:10.1016/j.heliyon.2023.e21314

Synthesis and analytical characterization of Ca-BTC metal organic framework

Munazza Ramzan, Malika Rani, Rabia Siddiqui, Aqeel Ahmad Shah, Maryam Arshad, Muhammad Wasif Ghauri, Ghazanfar Abbas, Kareem Yusuf, Mika Sillanpää

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Metal Organic framework (MOF) has been a class of great interest during the past few years owing to its decidedly applicative, easily synthesized and improved characteristics. Ca-BTC MOF is synthesized by Hydrothermal technique and reported for the first time. Its structural morphology was analyzed using XRD, SEM, and EDS, showing the tetragonal crystal structure having grain size of 24.92 nm and purity of sample respectively. FTIR, Raman Spectroscopy ensures the metal organic framework between Calcium and the tri-carboxylic group. Photoluminescence measures the energy gap of 3.792 eV, showing approximately the semiconducting behavior of synthesized material. Zeta potential having value of −13.5 mV confirms the instability having good microbial activity and conductivity i.e 0.290 mS/cm which reveals important insights into its electrical properties.

Original language	English
Article number	e21314
Journal	Heliyon
Volume	9
Issue number	11
DOIs	https://doi.org/10.1016/j.heliyon.2023.e21314
Publication status	Published - Nov 2023
Externally published	Yes

Keywords

EDS
FTIR
Hydrothermal technique
Photoluminescence
Raman spectroscopy
SEM
XRD
Zeta potential

ASJC Scopus subject areas

Multidisciplinary

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10.1016/j.heliyon.2023.e21314

Cite this

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title = "Synthesis and analytical characterization of Ca-BTC metal organic framework",

abstract = "Metal Organic framework (MOF) has been a class of great interest during the past few years owing to its decidedly applicative, easily synthesized and improved characteristics. Ca-BTC MOF is synthesized by Hydrothermal technique and reported for the first time. Its structural morphology was analyzed using XRD, SEM, and EDS, showing the tetragonal crystal structure having grain size of 24.92 nm and purity of sample respectively. FTIR, Raman Spectroscopy ensures the metal organic framework between Calcium and the tri-carboxylic group. Photoluminescence measures the energy gap of 3.792 eV, showing approximately the semiconducting behavior of synthesized material. Zeta potential having value of −13.5 mV confirms the instability having good microbial activity and conductivity i.e 0.290 mS/cm which reveals important insights into its electrical properties.",

keywords = "EDS, FTIR, Hydrothermal technique, Photoluminescence, Raman spectroscopy, SEM, XRD, Zeta potential",

author = "Munazza Ramzan and Malika Rani and Rabia Siddiqui and {Ahmad Shah}, Aqeel and Maryam Arshad and Ghauri, {Muhammad Wasif} and Ghazanfar Abbas and Kareem Yusuf and Mika Sillanp{\"a}{\"a}",

note = "Publisher Copyright: {\textcopyright} 2023 The Authors",

year = "2023",

month = nov,

doi = "10.1016/j.heliyon.2023.e21314",

language = "English",

volume = "9",

journal = "Heliyon",

issn = "2405-8440",

publisher = "Elsevier BV",

number = "11",

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TY - JOUR

T1 - Synthesis and analytical characterization of Ca-BTC metal organic framework

AU - Ramzan, Munazza

AU - Rani, Malika

AU - Siddiqui, Rabia

AU - Ahmad Shah, Aqeel

AU - Arshad, Maryam

AU - Ghauri, Muhammad Wasif

AU - Abbas, Ghazanfar

AU - Yusuf, Kareem

AU - Sillanpää, Mika

PY - 2023/11

Y1 - 2023/11

N2 - Metal Organic framework (MOF) has been a class of great interest during the past few years owing to its decidedly applicative, easily synthesized and improved characteristics. Ca-BTC MOF is synthesized by Hydrothermal technique and reported for the first time. Its structural morphology was analyzed using XRD, SEM, and EDS, showing the tetragonal crystal structure having grain size of 24.92 nm and purity of sample respectively. FTIR, Raman Spectroscopy ensures the metal organic framework between Calcium and the tri-carboxylic group. Photoluminescence measures the energy gap of 3.792 eV, showing approximately the semiconducting behavior of synthesized material. Zeta potential having value of −13.5 mV confirms the instability having good microbial activity and conductivity i.e 0.290 mS/cm which reveals important insights into its electrical properties.

AB - Metal Organic framework (MOF) has been a class of great interest during the past few years owing to its decidedly applicative, easily synthesized and improved characteristics. Ca-BTC MOF is synthesized by Hydrothermal technique and reported for the first time. Its structural morphology was analyzed using XRD, SEM, and EDS, showing the tetragonal crystal structure having grain size of 24.92 nm and purity of sample respectively. FTIR, Raman Spectroscopy ensures the metal organic framework between Calcium and the tri-carboxylic group. Photoluminescence measures the energy gap of 3.792 eV, showing approximately the semiconducting behavior of synthesized material. Zeta potential having value of −13.5 mV confirms the instability having good microbial activity and conductivity i.e 0.290 mS/cm which reveals important insights into its electrical properties.

KW - EDS

KW - FTIR

KW - Hydrothermal technique

KW - Photoluminescence

KW - Raman spectroscopy

KW - SEM

KW - XRD

KW - Zeta potential

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U2 - 10.1016/j.heliyon.2023.e21314

DO - 10.1016/j.heliyon.2023.e21314

M3 - Article

AN - SCOPUS:85175253586

SN - 2405-8440

VL - 9

JO - Heliyon

JF - Heliyon

IS - 11

M1 - e21314

ER -

Synthesis and analytical characterization of Ca-BTC metal organic framework

Abstract

Keywords

ASJC Scopus subject areas

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New Data from Women University Illuminate Research in Science and Technology (Synthesis and analytical characterization of Ca-BTC metal organic framework)

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Synthesis and analytical characterization of Ca-BTC metal organic framework

Abstract

Keywords

ASJC Scopus subject areas

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New Data from Women University Illuminate Research in Science and Technology (Synthesis and analytical characterization of Ca-BTC metal organic framework)

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