TY - JOUR
T1 - Super tough interpenetrating polymeric network of styrene butadiene rubber-poly(methyl methacrylate) incorporated with general purpose carbon black (N660)
AU - James, Jose
AU - Thomas, George Vazhathara
AU - Sisanth, Krishanagegham Sidharathan
AU - Maria, Hanna Joseph
AU - Rouxel, Didier
AU - Strankowski, Michal
AU - Kalarikkal, Nandakumar
AU - Laroze, David
AU - Oluwafemi, Oluwatobi Samuel
AU - Volova, Tatiana
AU - Thomas, Sabu
N1 - Publisher Copyright:
© 2022 Wiley Periodicals LLC.
PY - 2022/10/20
Y1 - 2022/10/20
N2 - A classic set of polymeric interpenetrating polymeric network (IPN) micro-composites has been fabricated using an elastomer—styrene butadiene rubber [SBR], a thermoplastic poly(methyl methacrylate)-PMMA and with carbon black (CB)-N660 as a filler and reinforcing agent. This synthesized IPN composite can be promisingly employed as a toughened plastic and vibrational damper in a wide service range with excellent thermal stability, optimum storage modulus, and co-continuous morphological pattern. transmission electron microscopy, scanning electron microscopy, atomic force microscopy, and Raman imaging are successfully employed for the morphological characterization. Mechanical, thermal, viscoelastic, and damping features of IPN composites have been carefully studied in detail and compared with parent polymers, corresponding IPN, and composites. The double network formation of filler CB and plastic component PMMA form an intercalated morphological pattern in the SBR matrix with 20 times enhancement in toughness value compared with neat SBR. The fabrication and characterization adopted in this work can definitely act as a platform for the design of new toughened material with excellent performance and cost-effectiveness.
AB - A classic set of polymeric interpenetrating polymeric network (IPN) micro-composites has been fabricated using an elastomer—styrene butadiene rubber [SBR], a thermoplastic poly(methyl methacrylate)-PMMA and with carbon black (CB)-N660 as a filler and reinforcing agent. This synthesized IPN composite can be promisingly employed as a toughened plastic and vibrational damper in a wide service range with excellent thermal stability, optimum storage modulus, and co-continuous morphological pattern. transmission electron microscopy, scanning electron microscopy, atomic force microscopy, and Raman imaging are successfully employed for the morphological characterization. Mechanical, thermal, viscoelastic, and damping features of IPN composites have been carefully studied in detail and compared with parent polymers, corresponding IPN, and composites. The double network formation of filler CB and plastic component PMMA form an intercalated morphological pattern in the SBR matrix with 20 times enhancement in toughness value compared with neat SBR. The fabrication and characterization adopted in this work can definitely act as a platform for the design of new toughened material with excellent performance and cost-effectiveness.
KW - IPN
KW - IPN composite
KW - carbon black
KW - rubber composites
KW - toughed composites
UR - http://www.scopus.com/inward/record.url?scp=85135826589&partnerID=8YFLogxK
U2 - 10.1002/app.52978
DO - 10.1002/app.52978
M3 - Article
AN - SCOPUS:85135826589
SN - 0021-8995
VL - 139
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 40
M1 - e52978
ER -