Subcomponent assembly and transmetalation of dinuclear helicates

Johannes Dömer; J. Chris Slootweg; Florian Hupka; Koop Lammertsma; F. Ekkehardt Hahn

doi:10.1002/anie.201002776

Subcomponent assembly and transmetalation of dinuclear helicates

Johannes Dömer
, J. Chris Slootweg
, Florian Hupka
, Koop Lammertsma
, F. Ekkehardt Hahn

University of Münster

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

Only available as helicates: Dinuclear zinc and nickel complexes bearing previously inaccessible N,S-N,S ligands have been obtained in subcomponent self-assembly reactions from complexes bearing two 2-thiolatobenzaldehyde ligands and 4,4'- diaminodiphenylmethane. Both complexes react with Pd(OAc)2 by transmetalation to give the dinuclear palladium complex (see scheme).

Original language	English
Pages (from-to)	6430-6433
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	36
DOIs	https://doi.org/10.1002/anie.201002776
Publication status	Published - 23 Aug 2010
Externally published	Yes

Keywords

Helical structures
N ligands
S ligands
Schiff bases
Self-assembly

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201002776

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abstract = "Only available as helicates: Dinuclear zinc and nickel complexes bearing previously inaccessible N,S-N,S ligands have been obtained in subcomponent self-assembly reactions from complexes bearing two 2-thiolatobenzaldehyde ligands and 4,4'- diaminodiphenylmethane. Both complexes react with Pd(OAc)2 by transmetalation to give the dinuclear palladium complex (see scheme).",

keywords = "Helical structures, N ligands, S ligands, Schiff bases, Self-assembly",

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T1 - Subcomponent assembly and transmetalation of dinuclear helicates

AU - Dömer, Johannes

AU - Slootweg, J. Chris

AU - Hupka, Florian

AU - Lammertsma, Koop

AU - Hahn, F. Ekkehardt

PY - 2010/8/23

Y1 - 2010/8/23

N2 - Only available as helicates: Dinuclear zinc and nickel complexes bearing previously inaccessible N,S-N,S ligands have been obtained in subcomponent self-assembly reactions from complexes bearing two 2-thiolatobenzaldehyde ligands and 4,4'- diaminodiphenylmethane. Both complexes react with Pd(OAc)2 by transmetalation to give the dinuclear palladium complex (see scheme).

AB - Only available as helicates: Dinuclear zinc and nickel complexes bearing previously inaccessible N,S-N,S ligands have been obtained in subcomponent self-assembly reactions from complexes bearing two 2-thiolatobenzaldehyde ligands and 4,4'- diaminodiphenylmethane. Both complexes react with Pd(OAc)2 by transmetalation to give the dinuclear palladium complex (see scheme).

KW - Helical structures

KW - N ligands

KW - S ligands

KW - Schiff bases

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/77956019611

U2 - 10.1002/anie.201002776

DO - 10.1002/anie.201002776

M3 - Article

AN - SCOPUS:77956019611

SN - 1433-7851

VL - 49

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Subcomponent assembly and transmetalation of dinuclear helicates

Abstract

Keywords

ASJC Scopus subject areas

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