Subcomponent assembly and transmetalation of dinuclear helicates

Johannes Dömer, J. Chris Slootweg, Florian Hupka, Koop Lammertsma, F. Ekkehardt Hahn

Research output: Contribution to journalArticlepeer-review

65 Citations (Scopus)

Abstract

Only available as helicates: Dinuclear zinc and nickel complexes bearing previously inaccessible N,S-N,S ligands have been obtained in subcomponent self-assembly reactions from complexes bearing two 2-thiolatobenzaldehyde ligands and 4,4'- diaminodiphenylmethane. Both complexes react with Pd(OAc)2 by transmetalation to give the dinuclear palladium complex (see scheme).

Original languageEnglish
Pages (from-to)6430-6433
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number36
DOIs
Publication statusPublished - 23 Aug 2010
Externally publishedYes

Keywords

  • Helical structures
  • N ligands
  • S ligands
  • Schiff bases
  • Self-assembly

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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